Issue 9, 2022

Nitrogen-doped molecular bowls as electron donors in photoinduced electron transfer reactions

Abstract

In recent years, the chemistry of curved π-conjugated molecules has experienced a sharp rise. The inclusion of a heteroatom in the carbon network significantly affects its semiconducting properties. In this work, we computationally study the photoinduced electron transfer in a series of C60 fullerene complexes with experimentally established nitrogen-doped molecular bowls. Our results demonstrate that introducing nitrogen into pentagonal rings of the bowl-shaped π-conjugated molecules and extending the π-conjugation can modulate their electron-transfer properties. Among the studied complexes, the hub-NCor⊃C60 complex exhibits the most desirable combination of ultrafast charge separation and slow charge recombination, suggesting its potential use in photovoltaics.

Graphical abstract: Nitrogen-doped molecular bowls as electron donors in photoinduced electron transfer reactions

Supplementary files

Article information

Article type
Paper
Submitted
10 3月 2022
Accepted
27 3月 2022
First published
30 3月 2022
This article is Open Access
Creative Commons BY-NC license

Nanoscale Adv., 2022,4, 2180-2188

Nitrogen-doped molecular bowls as electron donors in photoinduced electron transfer reactions

O. A. Stasyuk, A. J. Stasyuk, M. Solà and A. A. Voityuk, Nanoscale Adv., 2022, 4, 2180 DOI: 10.1039/D2NA00150K

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements