Issue 3, 2019

Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

Abstract

The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K (Image ID:c8cp07160h-t1.gif) and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J′/J| = 3.3 × 10−3, demonstrating a high degree of isolation for the Cu chains.

Graphical abstract: Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

Supplementary files

Article information

Article type
Communication
Submitted
20 11月 2018
Accepted
14 12月 2018
First published
14 12月 2018
This article is Open Access
Creative Commons BY-NC license

Phys. Chem. Chem. Phys., 2019,21, 1014-1018

Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

B. M. Huddart, J. Brambleby, T. Lancaster, P. A. Goddard, F. Xiao, S. J. Blundell, F. L. Pratt, J. Singleton, P. Macchi, R. Scatena, A. M. Barton and J. L. Manson, Phys. Chem. Chem. Phys., 2019, 21, 1014 DOI: 10.1039/C8CP07160H

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