Issue 48, 2018

Enhanced annihilation electrochemiluminescence by nanofluidic confinement

Abstract

Microfabricated nanofluidic electrochemical devices offer a highly controlled nanochannel geometry; they confine the volume of chemical reactions to the nanoscale and enable greatly amplified electrochemical detection. Here, the generation of stable light emission by electrochemiluminescence (ECL) in transparent nanofluidic devices is demonstrated for the first time by exploiting nanogap amplification. Through continuous oxidation and reduction of [Ru(bpy)3]2+ luminophores at electrodes positioned at opposite walls of a 100 nm nanochannel, we compare classic redox cycling and ECL annihilation. Enhanced ECL light emission of attomole luminophore quantities is evidenced under ambient conditions due to the spatial confinement in a 10 femtoliter volume, resulting in a short diffusion timescale and highly efficient ECL reaction pathways at the nanoscale.

Graphical abstract: Enhanced annihilation electrochemiluminescence by nanofluidic confinement

Supplementary files

Article information

Article type
Edge Article
Submitted
19 7月 2018
Accepted
30 9月 2018
First published
01 10月 2018
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2018,9, 8946-8950

Enhanced annihilation electrochemiluminescence by nanofluidic confinement

H. Al-Kutubi, S. Voci, L. Rassaei, N. Sojic and K. Mathwig, Chem. Sci., 2018, 9, 8946 DOI: 10.1039/C8SC03209B

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