Issue 36, 2018

Alkali metal complexes based on bisheterocyclomethanide ligands

Abstract

A series of new alkali metal complexes containing deprotonated bisheterocyclomethanide were synthesised and structurally as well as spectroscopically characterised. Starting from the neutral bis-(benzoxazol-2-yl)methane ({NCOC6H4}2CH2), the complexes were obtained by facile deprotonation of the methylene bridge with nbutyllithium (nBuLi) or potassium hydride. Each of the resulting complexes [({NCOC6H4}2CH)Li(OEt2)2] (1), [({NCOC6H4}2CH)K(thf)]n (2) and [({NCOC6H4}2CH)K(18-crown-6)]n (3) (n → ∞) was analysed in the solid state by single crystal X-ray diffraction and in solution by various NMR techniques. All the compounds show a nearly planar ligand with the alkali metal ion chelated by the two ring nitrogen atoms of the conjugated C3N2 moiety. Furthermore, water NMR titration experiments revealed that both compounds 2 and 3 are examples of water-stable reactive organo potassium compounds. Due to their hydrolysis stability, these complexes are under further investigations in deep eutectic solvents.

Graphical abstract: Alkali metal complexes based on bisheterocyclomethanide ligands

Supplementary files

Article information

Article type
Paper
Submitted
27 4月 2018
Accepted
07 6月 2018
First published
12 6月 2018
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2018,47, 12606-12612

Alkali metal complexes based on bisheterocyclomethanide ligands

J. Kretsch, A. Kreyenschmidt, R. Herbst-Irmer and D. Stalke, Dalton Trans., 2018, 47, 12606 DOI: 10.1039/C8DT01678J

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements