Issue 1, 2018

Photoswitchable nonlinear optical properties of metal complexes

Abstract

Incorporating photosensitive molecules into the organic/inorganic hybrid materials can contribute to forming photoresponsive systems. The second/third-order nonlinear optical properties can be changed via external light stimulation at an appropriate wavelength. The photochromic metal complexes appear to be superior promising materials in the domain of photoswitchable nonlinear optics (NLO). Thus, the purpose of this review is to examine current progress of metal complexes in the field of photoswitchable NLO materials and provide perspectives for the future. The overview includes the second-order and third-order NLO photoswitches and NLO properties of metal complexes. Combined with the characteristics of pyrene and stilbazolium groups, we describe a new type of photoswitchable NLO materials. The rapidly increasing investigations in this domain suggest that NLO photoswitches of metal complexes would play a critical role for inspiring applications in the future.

Graphical abstract: Photoswitchable nonlinear optical properties of metal complexes

Article information

Article type
Perspective
Submitted
24 10月 2017
Accepted
14 11月 2017
First published
14 11月 2017

Dalton Trans., 2018,47, 13-22

Photoswitchable nonlinear optical properties of metal complexes

X. Xue, H. Wang, Y. Han and H. Hou, Dalton Trans., 2018, 47, 13 DOI: 10.1039/C7DT03989A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements