Issue 9, 2018

Carrier-doped aromatic hydrocarbons: a new platform in condensed matter chemistry and physics

Abstract

High-quality bulk samples of the first four polyacenes, which are naphthalene, anthracene, tetracene, and pentacene, doped with alkali metal in 1 : 1 and 1 : 2 stoichiometries were prepared and their fundamental properties were systematically studied. A new systematic understanding on the electronic states of electron-doped polyacenes sensitive to the energetic balance among on-site Coulomb repulsion, bandwidth and the Peierls instability was provided. The carrier-doped typical aromatic hydrocarbons showed a large variety of properties as well as charge transfer complexes and metal-doped fullerides. We open a new avenue for organometallic and inorganic chemistry.

Graphical abstract: Carrier-doped aromatic hydrocarbons: a new platform in condensed matter chemistry and physics

Article information

Article type
Perspective
Submitted
05 10月 2017
Accepted
18 1月 2018
First published
18 1月 2018

Dalton Trans., 2018,47, 2881-2895

Carrier-doped aromatic hydrocarbons: a new platform in condensed matter chemistry and physics

S. Heguri and K. Tanigaki, Dalton Trans., 2018, 47, 2881 DOI: 10.1039/C7DT03745G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements