Issue 10, 2018

Directing the mechanism of CO2 reduction by a Mn catalyst through surface immobilization

Abstract

Immobilization of a Mn polypyridyl CO2 reduction electrocatalyst on nanocrystalline TiO2 electrodes yields an active heterogeneous system and also significantly triggers a change in voltammetric and catalytic behaviour, relative to in solution. A combination of spectroelectrochemical techniques are presented here to elucidate the mechanism of the immobilized catalyst in situ.

Graphical abstract: Directing the mechanism of CO2 reduction by a Mn catalyst through surface immobilization

Supplementary files

Article information

Article type
Communication
Submitted
20 12月 2017
Accepted
19 2月 2018
First published
19 2月 2018

Phys. Chem. Chem. Phys., 2018,20, 6811-6816

Directing the mechanism of CO2 reduction by a Mn catalyst through surface immobilization

J. J. Walsh, M. Forster, C. L. Smith, G. Neri, R. J. Potter and A. J. Cowan, Phys. Chem. Chem. Phys., 2018, 20, 6811 DOI: 10.1039/C7CP08537K

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