Issue 18, 2018

Electrochemical initiation of electron-catalyzed phenanthridine synthesis by trifluoromethylation of isonitriles

Abstract

The electron-catalyzed formation of phenanthridines starting from isonitriles initiated by an electrochemical reduction of the Togni reagent is presented. The required number of faradays per mole of starting material and the respective yields clearly show the catalytic character of the electron in this reaction. The mechanism is supported by cyclic voltammetry experiments.

Graphical abstract: Electrochemical initiation of electron-catalyzed phenanthridine synthesis by trifluoromethylation of isonitriles

Supplementary files

Article information

Article type
Communication
Submitted
04 12月 2017
Accepted
03 1月 2018
First published
12 2月 2018
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2018,54, 2240-2243

Electrochemical initiation of electron-catalyzed phenanthridine synthesis by trifluoromethylation of isonitriles

M. Lübbesmeyer, D. Leifert, H. Schäfer and A. Studer, Chem. Commun., 2018, 54, 2240 DOI: 10.1039/C7CC09302K

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