Issue 8, 2017

A concise synthetic approach to parvistemin A and (±)-diperezone

Abstract

A concise synthetic approach to symmetric biquinone skeletons has been developed through a new biomimetic oxidative phenolic coupling of 1,2,4-trihydroxyarenes using K3[Fe(CN)6] or FeCl3 as the oxidant under basic conditions. Merging with the ring expansion process of cyclobutenones, a synthetic strategy to biquinone natural products has been developed. And in the light of this strategy, total syntheses of parvistemin A and (±)-diperezone have been achieved.

Graphical abstract: A concise synthetic approach to parvistemin A and (±)-diperezone

Supplementary files

Article information

Article type
Research Article
Submitted
18 3月 2017
Accepted
23 4月 2017
First published
27 4月 2017

Org. Chem. Front., 2017,4, 1493-1498

A concise synthetic approach to parvistemin A and (±)-diperezone

S. Gao and X. Hu, Org. Chem. Front., 2017, 4, 1493 DOI: 10.1039/C7QO00216E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements