Issue 7, 2017

Copper-catalyzed highly selective approach to 2-boroallylic silanes from allenylsilanes

Abstract

A highly chemo- and regioselective copper-catalyzed borylcupration of 1,2-allenylsilanes affords 2-borylallylsilanes by applying the ligand effect. Many synthetically attractive functional groups are well tolerated. As demonstrated, such 2-borylallylsilanes are very useful dimetallic reagents in organic synthesis. A rationale for the regioselectivity switch is provided.

Graphical abstract: Copper-catalyzed highly selective approach to 2-boroallylic silanes from allenylsilanes

Supplementary files

Article information

Article type
Research Article
Submitted
18 2月 2017
Accepted
20 3月 2017
First published
21 3月 2017

Org. Chem. Front., 2017,4, 1261-1265

Copper-catalyzed highly selective approach to 2-boroallylic silanes from allenylsilanes

L. Song, W. Yuan and S. Ma, Org. Chem. Front., 2017, 4, 1261 DOI: 10.1039/C7QO00135E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements