Issue 5, 2017

Structures and applications of metal–organic frameworks featuring metal clusters

Abstract

Metal–organic frameworks (MOFs), self-assembled from metal ions or metal clusters with organic ligands, are well known for their intriguing structure, permanent porosity, and tunable properties and have shown great prospect for various applications. In the present review, we mainly highlight recent significant examples of metal clusters in our team and provide a comprehensive review on the structure of metal cluster-based MOFs and their applications including for sensing metal ions, small molecules and gases, nitroaromatics and explosives, as well as many other applications. We classified two different coordination polymers: (i) homometallic coordination polymers (examples of coordination polymers with single and mixed types of secondary building units) and (ii) heterometallic coordination polymers (examples of coordination polymers based on metal–oxygen clusters and W–Cu–S clusters).

Graphical abstract: Structures and applications of metal–organic frameworks featuring metal clusters

Article information

Article type
Highlight
Submitted
02 11月 2016
Accepted
02 12月 2016
First published
02 12月 2016

CrystEngComm, 2017,19, 745-757

Structures and applications of metal–organic frameworks featuring metal clusters

L. Qin and H. Zheng, CrystEngComm, 2017, 19, 745 DOI: 10.1039/C6CE02293F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements