Issue 3, 2016

Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

Abstract

The halogenation of metallapentalyne led to the formation of metallapentalenes, which were fully characterized and studied by DFT calculations. The experimental and computational studies indicate that four resonance forms contribute to the overall structure of the metallapentalenes, and one resonance form could be viewed as the first examples of metallaiodirenium and metallabromirenium ions.

Graphical abstract: Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

Supplementary files

Article information

Article type
Edge Article
Submitted
20 10月 2015
Accepted
17 11月 2015
First published
23 11月 2015
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2016,7, 1815-1818

Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

M. Luo, C. Zhu, L. Chen, H. Zhang and H. Xia, Chem. Sci., 2016, 7, 1815 DOI: 10.1039/C5SC03963K

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