Issue 2, 2016

Highly effective sites and selectivity of nitrogen-doped graphene/CNT catalysts for CO2 electrochemical reduction

Abstract

Metal-free catalysts, such as graphene/carbon nanostructures, are highly cost-effective to replace expensive noble metals for CO2 reduction if fundamental issues, such as active sites and selectivity, are clearly understood. Using both density functional theory (DFT) and ab initio molecular dynamic calculations, we show that the interplay of N-doping and curvature can effectively tune the activity and selectivity of graphene/carbon-nanotube (CNT) catalysts. The CO2 activation barrier can be optimized to 0.58 eV for graphitic-N doped graphene edges, compared with 1.3 eV in the un-doped counterpart. The graphene catalyst without curvature shows strong selectivity for CO/HCOOH production, whereas the (6, 0) CNT with a high degree of curvature is effective for both CH3OH and HCHO production. Curvature is also very influential to tune the overpotential for a given product, e.g. from 1.5 to 0.02 V for CO production and from 1.29 to 0.49 V for CH3OH production. Hence, the graphene/CNT nanostructures offer great scope and flexibility for effective tunning of catalyst efficiency and selectivity, as shown here for CO2 reduction.

Graphical abstract: Highly effective sites and selectivity of nitrogen-doped graphene/CNT catalysts for CO2 electrochemical reduction

Supplementary files

Article information

Article type
Edge Article
Submitted
29 9月 2015
Accepted
11 11月 2015
First published
12 11月 2015
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2016,7, 1268-1275

Author version available

Highly effective sites and selectivity of nitrogen-doped graphene/CNT catalysts for CO2 electrochemical reduction

G. Chai and Z. Guo, Chem. Sci., 2016, 7, 1268 DOI: 10.1039/C5SC03695J

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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