Issue 10, 2016

Realizing omnidirectional light harvesting by employing hierarchical architecture for dye sensitized solar cells

Abstract

To improve the omnidirectional light-harvesting in dye-sensitized solar cells (DSSCs), here we present a dandelion-like structure composed of ZnO hemispherical shells and nanorods. Uniformly distributed hemispherical shells effectively suppress the reflection over the broadband region at incident angles up to 60°, greatly improving the optical absorption of the DSSCs. In addition, modulating the length of the ZnO nanorods controls the omnidirectional characteristics of DSSCs. This phenomenon is attributed to the degree of periodicity of the ZnO dandelion-like structures. Cells with shorter rods exhibit a high degree of periodicity, thus the conversion efficiencies of the cells show specific angle-independent features. On the other hand, the cells with longer lengths reveal angle-dependent photovoltaic performance. Along with the simulation, the cells with dandelion-like ZnO structures can couple incident photons efficiently to achieve excellent broadband and omnidirectional light-harvesting performances experimentally, and the DSSCs enhanced the conversion efficiency by 48% at large incident angles. All these findings not only provide further insight into the light-trapping mechanism in these complex three-dimensional nanostructures but also offer efficient omnidirectional and broadband nanostructured photovoltaics for advanced applications.

Graphical abstract: Realizing omnidirectional light harvesting by employing hierarchical architecture for dye sensitized solar cells

Article information

Article type
Paper
Submitted
11 11月 2015
Accepted
26 1月 2016
First published
01 2月 2016

Nanoscale, 2016,8, 5478-5487

Realizing omnidirectional light harvesting by employing hierarchical architecture for dye sensitized solar cells

M. Hsieh, F. Lai, W. Chen, M. Hsieh, H. Hu, P. Yu, H. Kuo and S. Kuo, Nanoscale, 2016, 8, 5478 DOI: 10.1039/C5NR07948A

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