Issue 29, 2016

Detecting levels of polyquaternium-10 (PQ-10) via potentiometric titration with dextran sulphate and monitoring the equivalence point with a polymeric membrane-based polyion sensor

Abstract

Polymeric quaternary ammonium salts (polyquaterniums) have found increasing use in industrial and cosmetic applications in recent years. More specifically, polyquaternium-10 (PQ-10) is routinely used in cosmetic applications as a conditioner in personal care product formulations. Herein, we demonstrate the use of potentiometric polyion-sensitive polymeric membrane-based electrodes to quantify PQ-10 levels. Mixtures containing both PQ-10 and sodium lauryl sulfate (SLS) are used as model samples to illustrate this new method. SLS is often present in cosmetic samples that contain PQ-10 (e.g., shampoos, etc.) and this surfactant species interferes with the polyion sensor detection chemistry. However, it is shown here that SLS can be readily separated from the PQ-10/SLS mixture by use of an anion-exchange resin and that the PQ-10 can then be titrated with dextran sulphate (DS). This titration is monitored by potentiometric polyanion sensors to provide equivalence points that are directly proportional to PQ-10 concentrations.

Graphical abstract: Detecting levels of polyquaternium-10 (PQ-10) via potentiometric titration with dextran sulphate and monitoring the equivalence point with a polymeric membrane-based polyion sensor

Article information

Article type
Paper
Submitted
18 6月 2016
Accepted
30 6月 2016
First published
04 7月 2016

Anal. Methods, 2016,8, 5806-5811

Detecting levels of polyquaternium-10 (PQ-10) via potentiometric titration with dextran sulphate and monitoring the equivalence point with a polymeric membrane-based polyion sensor

S. A. Ferguson, X. Wang and M. E. Meyerhoff, Anal. Methods, 2016, 8, 5806 DOI: 10.1039/C6AY01748G

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