Issue 87, 2014

Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

Abstract

Upon heating, lithium L-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.

Graphical abstract: Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
06 8月 2014
Accepted
08 9月 2014
First published
08 9月 2014

Chem. Commun., 2014,50, 13292-13295

Author version available

Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

H. H.-M. Yeung, M. Kosa, J. M. Griffin, C. P. Grey, D. T. Major and A. K. Cheetham, Chem. Commun., 2014, 50, 13292 DOI: 10.1039/C4CC06136E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements