Issue 58, 2014

Preparation of a “twisted basket” Mn4N8 cluster: a two-hydrogen-atom reduced analogue of the Mn4N8 pinned butterfly

Abstract

Mn4(μ-NHPh)4(μ-PhNNPh-κ2N,N′)2(py)4 (3) is synthesized via self assembly from dimeric Mn2(μ-NHPh)2(NR2)2 and PhNHNHPh (R = SiMe3). This cluster represents the N–N cleaved version of the previously-reported Mn4(μ-NHPh)23-PhNNPh-κ3N,N′)2(μ-PhNNPh-κ2N,N′)(py)4 “pinned butterfly” cluster (2), formally reduced by two hydrogen atoms. Cluster 2 may be converted to 3 by addition of N,N′-diphenylhydrazine as a two-electron reductant.

Graphical abstract: Preparation of a “twisted basket” Mn4N8 cluster: a two-hydrogen-atom reduced analogue of the Mn4N8 pinned butterfly

Supplementary files

Article information

Article type
Communication
Submitted
18 4月 2014
Accepted
15 5月 2014
First published
16 5月 2014

Chem. Commun., 2014,50, 7780-7782

Preparation of a “twisted basket” Mn4N8 cluster: a two-hydrogen-atom reduced analogue of the Mn4N8 pinned butterfly

M. R. Gau, C. R. Hamilton and M. J. Zdilla, Chem. Commun., 2014, 50, 7780 DOI: 10.1039/C4CC02872D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements