Issue 22, 2014

Catalyst-mediated yet catalyst-free hydrogels formed by interfacial chemical activation

Abstract

We introduce an entirely new method for forming hydrogels, wherein the formation is triggered by a catalyst, but the resulting hydrogels are catalyst-free. We unexpectedly found that a sufficient amount of crosslinkable catecholquinone/semiquinone free radicals is generated by the physical contact between catechol-containing polymers and surface-immobilized catalysts.

Graphical abstract: Catalyst-mediated yet catalyst-free hydrogels formed by interfacial chemical activation

Supplementary files

Article information

Article type
Communication
Submitted
27 11月 2013
Accepted
19 1月 2014
First published
20 1月 2014

Chem. Commun., 2014,50, 2869-2872

Catalyst-mediated yet catalyst-free hydrogels formed by interfacial chemical activation

E. Byun, J. H. Ryu and H. Lee, Chem. Commun., 2014, 50, 2869 DOI: 10.1039/C3CC49043B

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