Issue 40, 2014

Negative area compressibility in silver(i) tricyanomethanide

Abstract

The molecular framework Ag(tcm) (tcm = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

Graphical abstract: Negative area compressibility in silver(i) tricyanomethanide

Supplementary files

Article information

Article type
Communication
Submitted
13 9月 2013
Accepted
09 12月 2013
First published
09 12月 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 5264-5266

Negative area compressibility in silver(I) tricyanomethanide

S. A. Hodgson, J. Adamson, S. J. Hunt, M. J. Cliffe, A. B. Cairns, A. L. Thompson, M. G. Tucker, N. P. Funnell and A. L. Goodwin, Chem. Commun., 2014, 50, 5264 DOI: 10.1039/C3CC47032F

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