Issue 21, 2011

Anion-directed assembly of a three-dimensional metal–organic rotaxane framework

Abstract

A three-dimensional extended, metal–organic rotaxane framework (MORF) that incorporates encircled “struts” has been synthesized through a one-pot self-assembly process involving a macrocyclic tetraimidazolium “molecular box”, naphthalene dicaboxylate dianion, and Zn(II) cations. The present system represents progress towards controlling the features of three-dimensional metal–organic frameworks.

Graphical abstract: Anion-directed assembly of a three-dimensional metal–organic rotaxane framework

Supplementary files

Article information

Article type
Communication
Submitted
14 1月 2011
Accepted
15 2月 2011
First published
17 3月 2011

Chem. Commun., 2011,47, 5973-5975

Anion-directed assembly of a three-dimensional metal–organic rotaxane framework

H. Gong, B. M. Rambo, W. Cho, V. M. Lynch, M. Oh and J. L. Sessler, Chem. Commun., 2011, 47, 5973 DOI: 10.1039/C1CC10272A

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