Issue 90, 2020

Revisiting amorphous molybdenum sulfide's activity for the electro-driven reduction of dinitrogen and N-containing substrates

Abstract

Ammonia (NH3) is a major feedstock of the chemical industry. The imperious need to decarbonize its production has stimulated a quest for efficient catalysts able to drive the direct electro-reduction of dinitrogen (N2) into NH3. A large number of materials have now been proposed for this reaction, including bioinspired molybdenum sulfide derivatives. Here, we revisit the potential of amorphous molybdenum sulfide to drive the electrocatalytic reduction of N2 and other substrates of nitrogenase. We find that this material exhibits negligible activity towards N2 but achieves efficient reduction of inorganic azides.

Graphical abstract: Revisiting amorphous molybdenum sulfide's activity for the electro-driven reduction of dinitrogen and N-containing substrates

Supplementary files

Article information

Article type
Communication
Submitted
25 7月 2020
Accepted
13 10月 2020
First published
13 10月 2020

Chem. Commun., 2020,56, 13975-13978

Revisiting amorphous molybdenum sulfide's activity for the electro-driven reduction of dinitrogen and N-containing substrates

K. Yang, M. Koepf and V. Artero, Chem. Commun., 2020, 56, 13975 DOI: 10.1039/D0CC05078D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements