Issue 61, 2020

Metal–ligand cooperativity across two sites of a square planar iron(ii) complex ligated by a tetradentate PNNP ligand

Abstract

An iron(II) complex with a square planar geometry and S = 1 ground state was synthesized using a rigid tetradentate bisphosphine-bisamide [PNNP]2− ligand. This complex was shown to bind an equivalent of PMe3 to produce a five-coordinate low spin complex, and to react with two equivalents of borane reagents via addition of two B–H bonds across the metal–amide bonds in a metal–ligand cooperative fashion.

Graphical abstract: Metal–ligand cooperativity across two sites of a square planar iron(ii) complex ligated by a tetradentate PNNP ligand

Supplementary files

Article information

Article type
Communication
Submitted
24 3月 2020
Accepted
17 6月 2020
First published
19 6月 2020

Chem. Commun., 2020,56, 8611-8614

Metal–ligand cooperativity across two sites of a square planar iron(II) complex ligated by a tetradentate PNNP ligand

G. P. Hatzis and C. M. Thomas, Chem. Commun., 2020, 56, 8611 DOI: 10.1039/D0CC02152K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements