Issue 27, 2019

Squeezing electrons out of 6s2 lone-pairs in perovskite-type oxides

Abstract

Having identified a set of conditions that predispose a solid-state ionic compound to a pressure-induced valence transition, we investigated a series of Bi(III) perovskite oxides. We found such a transition below 10 GPa in every case, including one that we synthesised for the first time (double perovskite-type Ba2BiOsO6).

Graphical abstract: Squeezing electrons out of 6s2 lone-pairs in perovskite-type oxides

  • This article is part of the themed collection: Perovskites

Supplementary files

Article information

Article type
Communication
Submitted
05 12月 2018
Accepted
11 3月 2019
First published
11 3月 2019

Chem. Commun., 2019,55, 3887-3890

Squeezing electrons out of 6s2 lone-pairs in perovskite-type oxides

C. Wang, P. Kayser, B. J. Kennedy, H. E. Maynard-Casely, Q. Gu and C. D. Ling, Chem. Commun., 2019, 55, 3887 DOI: 10.1039/C8CC09608B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements