Issue 18, 2017

All-inorganic quantum-dot light-emitting diodes based on perovskite emitters with low turn-on voltage and high humidity stability

Abstract

Recently, both light-to-electricity and electricity-to-light conversion efficiencies of perovskite achieved a breakthrough, e.g. 22.1% for solar cells and 11.7% for light-emitting diodes (LEDs), so the next fatal problem towards practical application, the device stability, became the key issue in this field. Here, we report all-inorganic LEDs including inorganic perovskite emitters (CsPbBr3) and inorganic charge transport layers (CTLs), with an emphasis on the significantly improved device stability. The quantum dot LEDs (QLEDs) were fabricated according to ITO/NiO/CsPbBr3 QDs/ZnO/Al device configuration. On the one hand, the all-inorganic LED lifetime under 65% humidity corresponding to a 70% electroluminescence (EL) conservation rate can be improved up to 3.5 times when compared with LEDs adopting conventional organic CTLs due to the intrinsic chemical stability of these inorganic CTLs and their less hydrophilic surfaces. Furthermore, as a surprise, the bare all-inorganic LED without encapsulation can work in water for about 20 seconds, which is over 10 times more sustainable than the organic–inorganic LED, which proves the excellent water-isolation ability. On the other hand, the all-inorganic QLEDs show the lowest turn-on voltage of 2.4 V among all the reported CsPbBr3 QLEDs because the inorganic CTLs possess well-matched energy band alignments with CsPbBr3, and hence result in efficient carrier injection. This work paves the way to constructing all-inorganic devices for stable perovskite photovoltaic and light-emitting devices.

Graphical abstract: All-inorganic quantum-dot light-emitting diodes based on perovskite emitters with low turn-on voltage and high humidity stability

Supplementary files

Article information

Article type
Paper
Submitted
24 12月 2016
Accepted
06 4月 2017
First published
10 4月 2017

J. Mater. Chem. C, 2017,5, 4565-4570

All-inorganic quantum-dot light-emitting diodes based on perovskite emitters with low turn-on voltage and high humidity stability

Q. Shan, J. Li, J. Song, Y. Zou, L. Xu, J. Xue, Y. Dong, C. Huo, J. Chen, B. Han and H. Zeng, J. Mater. Chem. C, 2017, 5, 4565 DOI: 10.1039/C6TC05578H

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