Issue 26, 2017

Alkoxido-bridged binuclear copper(ii) complexes derived from aminoalcohols – useful building blocks in designing coordination polymers with a rich structural variety

Abstract

The reactions of copper(II) salts with aminoalcohols frequently afford alkoxido-bridged dimers. Neutral (e.g. bis(4-pyridyl) derivatives) or anionic divergent ligands (e.g. polycarboxylate anions, polycyanido-metallates) are employed as spacers. In this paper, a rich variety of structures are reviewed, emphasizing the role played by the denticity of the aminoalcohols and of the linkers, as well as by the accompanying anions, in the network topology. The involvement of coordinative and non-covalent bonds (π–π stacking, argentophilic/aurophilic, π⋯Hg interactions, hydrogen bonds) in sustaining the solid-state architectures is also discussed.

Graphical abstract: Alkoxido-bridged binuclear copper(ii) complexes derived from aminoalcohols – useful building blocks in designing coordination polymers with a rich structural variety

Article information

Article type
Highlight
Submitted
26 4月 2017
Accepted
07 6月 2017
First published
07 6月 2017

CrystEngComm, 2017,19, 3538-3552

Alkoxido-bridged binuclear copper(II) complexes derived from aminoalcohols – useful building blocks in designing coordination polymers with a rich structural variety

T. Mocanu, V. Tudor and M. Andruh, CrystEngComm, 2017, 19, 3538 DOI: 10.1039/C7CE00798A

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