Issue 40, 2014

Enhanced oxidative stability of non-Grignard magnesium electrolytes through ligand modification

Abstract

A series of non-Grignard Mg-electrolytes with various para-substituents was synthesized starting from commercially-available phenols. More electron-withdrawing substituents shift the anodic stability of the electrolyte by 400 mV. The p-CF3 substituted phenol exhibits the highest stability of 2.9 V vs. Mg2+/0, and cycles reversibly with the Chevrel-phase Mo6S8 Mg-ion cathode.

Graphical abstract: Enhanced oxidative stability of non-Grignard magnesium electrolytes through ligand modification

Supplementary files

Article information

Article type
Communication
Submitted
23 9月 2013
Accepted
25 11月 2013
First published
26 11月 2013

Chem. Commun., 2014,50, 5193-5195

Enhanced oxidative stability of non-Grignard magnesium electrolytes through ligand modification

E. G. Nelson, J. W. Kampf and B. M. Bartlett, Chem. Commun., 2014, 50, 5193 DOI: 10.1039/C3CC47277A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements