Issue 14, 2012

Influence of ligand field stabilization energy on the elastic properties of multiferroic MOFs with the perovskite architecture

Abstract

We report the mechanical properties of four isostructural metal–organic frameworks (MOFs) that adopt the ABX3 perovskite topology: [(CH3)2NH2]M(HCOO)3, where M = divalent Mn, Co, Ni, and Zn. Their Young's moduli were measured via single-crystal nanoindentation. We show that the mechanical stability of such isostructural frameworks with octahedral coordination increases with greater ligand field stabilization energy (LFSE).

Graphical abstract: Influence of ligand field stabilization energy on the elastic properties of multiferroic MOFs with the perovskite architecture

Supplementary files

Article information

Article type
Communication
Submitted
30 11月 2011
Accepted
08 1月 2012
First published
02 2月 2012

Dalton Trans., 2012,41, 3949-3952

Influence of ligand field stabilization energy on the elastic properties of multiferroic MOFs with the perovskite architecture

J. Tan, P. Jain and A. K. Cheetham, Dalton Trans., 2012, 41, 3949 DOI: 10.1039/C2DT12300B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements