Issue 5, 2018
From the journal:

Chemical Communications

Carbodiimides as catalysts for the reduction of a cadmium hydride complex†

D. J. Webb,a   C. M. Fitchett, ORCID logo b   M. Lein ORCID logo a  and  J. R. Fulton ORCID logo *a  

* Corresponding authors

a School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New Zealand
E-mail: j.robin.fulton@vuw.ac.nz

b Department of Chemistry, University of Canterbury, P.B. 4800, Christchurch 8041, New Zealand

Abstract

A rare terminal cadmium hydride complex [(BDI)CdH] (BDI = [{N(2,6-iPr2C6H3)C(Me)}2CH]) has been synthesised from [(BDI)CdCl] and LiEt3BH. The hydride can be reduced to the cadmium(I) dimer, [(BDI)CdCd(BDI)] upon treatment with a catalytic amount of diisopropyl- or dicyclohexylcarbodiimide.

Graphical abstract: Carbodiimides as catalysts for the reduction of a cadmium hydride complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC08393A
Article type
Communication
Submitted
01 十一月 2017
Accepted
04 十二月 2017
First published
04 十二月 2017

Chem. Commun., 2018,54, 460-462

Permissions

Request permissions

Carbodiimides as catalysts for the reduction of a cadmium hydride complex

D. J. Webb, C. M. Fitchett, M. Lein and J. R. Fulton, Chem. Commun., 2018, 54, 460 DOI: 10.1039/C7CC08393A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements