Issue 25, 2010

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex

Abstract

The synthesis and characterization of two-coordinate cobalt(II) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment.

Graphical abstract: Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex

Supplementary files

Article information

Article type
Communication
Submitted
22 一月 2010
Accepted
15 四月 2010
First published
20 五月 2010

Chem. Commun., 2010,46, 4466-4468

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex

C. Ni, T. A. Stich, G. J. Long and P. P. Power, Chem. Commun., 2010, 46, 4466 DOI: 10.1039/C001483D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements