Atomic spectrometry update: review of advances in elemental speciation

Abstract

This is the 15^th Atomic Spectrometry Update (ASU) to focus on advances in elemental speciation and covers a period of approximately 12 months from January 2022. This ASU review deals with all aspects of the analytical atomic spectrometry speciation methods developed for: the determination of oxidation states; organometallic compounds; coordination compounds; metal and heteroatom-containing biomolecules, including metalloproteins, proteins, peptides and amino acids; and the use of metal-tagging to facilitate detection via atomic spectrometry. As with all ASU reviews the focus of the research reviewed includes those methods that incorporate atomic spectrometry as the measurement technique. However, because speciation analysis is inherently focused on the relationship between the metal(loid) atom and the organic moiety it is bound to, or incorporated within, atomic spectrometry alone cannot be the sole analytical approach of interest. For this reason molecular detection techniques are also included where they have provided a complementary approach to speciation analysis. This year the number of publications covered has fallen again along with the number of elements covered, most likely due to effects of the Covid-19 pandemic restricting laboratory access. The most popular elements remain as As, Hg and Se and the range of matrices under study is still broad with biological, environmental and foods being the most popular.