3D zinc@carbon fiber composite framework anode for aqueous Zn–MnO2 batteries

Abstract

Rechargeable aqueous batteries are one of the most promising large-scale energy storage devices because of their environment-friendly properties and high safety advantages without using flammable and poisonous organic liquid electrolyte. In addition, rechargeable Zn–MnO₂ batteries have great potential due to their low-cost resources as well as high energy density. However, dendritic growth of the zinc anode hinders the exertion of cycling stability and rate capacity in an aqueous Zn–MnO₂ battery system. Here we use an electrochemical deposition method to in situ form a three-dimensional (3D) zinc anode on carbon fibers (CFs). This 3D Zn@CFs framework has lower charge transfer resistance with larger electroactive areas. Batteries based on the 3D zinc framework anode and α-MnO₂ nanowire cathode present enhanced rate capacity and long cycling stability, which is promising for utilization in other zinc anode based aqueous batteries as an effective way to solve dendrite formation.