Issue 27, 2018

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes. The Ru–Rh complex can be decomposed in ionic liquids to metal nanoparticles.

Graphical abstract: Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

Supplementary files

Article information

Article type
Paper
Submitted
13 四月 2018
Accepted
07 五月 2018
First published
10 五月 2018

Dalton Trans., 2018,47, 8892-8896

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel and C. Janiak, Dalton Trans., 2018, 47, 8892 DOI: 10.1039/C8DT01455H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements