The first β-diketiminate ligated chlorosilylene has been synthesised and isolated from the corresponding β-diketiminato dichlorohydrosilane through dehydrochlorination with an N-heterocyclic carbene.
Y. Xiong, S. Yao, A. Kostenko and M. Driess, Dalton Trans., 2018, 47, 2152 DOI: 10.1039/C8DT00121A
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