Mono- and dinuclear tetraphosphabutadiene ferrate anions

Abstract

Reduction of [Cp^ArFe(μ-Br)]₂ (1, Cp^Ar = C₅(C₆H₄-4-Et)₅) by potassium napthalenide, followed by the addition of white phosphorus, affords [K(18-c-6){Cp^ArFe(η⁴-P₄)}] (2, 18-c-6 = [18]crown-6), which features a planar cyclo-P₄²⁻ ligand. The related diiron complex [Na₂(THF)₅(Cp^ArFe)₂(μ,η^4:4-P₄)] (3) was obtained by reducing 1 with sodium amalgam in the presence of P₄. Protonation of 3 affords [Na(THF)₃][(Cp^ArFe)₂(μ,η^4:4-P₄)(H)] (4), while the reaction of 3 with trimethylchlorosilane gives the nortricyclane compound P₇(SiMe₃)₃ as the main product.