Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.
R. Nolla-Saltiel, A. M. Geer, W. Lewis, A. J. Blake and D. L. Kays, Chem. Commun., 2018, 54, 1825 DOI: 10.1039/C7CC08385H
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