N-Heterocyclic carbene-stabilised arsinidene (AsH)

Adinarayana Doddi; Michael Weinhart; Alexander Hinz; Dirk Bockfeld; Jose M. Goicoechea; Manfred Scheer; Matthias Tamm

doi:10.1039/C7CC02628E

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N-Heterocyclic carbene-stabilised arsinidene (AsH)†

Adinarayana Doddi,^a Michael Weinhart,^b Alexander Hinz,^c Dirk Bockfeld,^a Jose M. Goicoechea,*^c Manfred Scheer

*^b and Matthias Tamm

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic and Analytical Chemistry, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, Germany
E-mail: m.tamm@tu-bs.de

^b Institute of Inorganic Chemistry, University of Regensburg, Universitätsstr. 31, 93040 Regensburg, Germany
E-mail: manfred.scheer@ur.de

^c Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford, UK
E-mail: jose.goicoechea@chem.ox.ac.uk

Abstract

N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe₃)₃ with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)_3.31][AsCO] with imidazolium chlorides.

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DOI: https://doi.org/10.1039/C7CC02628E
Article type: Communication
Submitted: 05 四月 2017
Accepted: 24 四月 2017
First published: 25 四月 2017

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Chem. Commun., 2017,53, 6069-6072

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N-Heterocyclic carbene-stabilised arsinidene (AsH)

A. Doddi, M. Weinhart, A. Hinz, D. Bockfeld, J. M. Goicoechea, M. Scheer and M. Tamm, Chem. Commun., 2017, 53, 6069 DOI: 10.1039/C7CC02628E

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Chemical Communications

N-Heterocyclic carbene-stabilised arsinidene (AsH)†

Abstract

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N-Heterocyclic carbene-stabilised arsinidene (AsH)

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