Issue 37, 2009
From the journal:

Chemical Communications

Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide†

Chengbao Nia  and  Philip P. Power*a  

* Corresponding authors

a University of California, One Shields Avenue, Davis, USA
E-mail: pppower@ucdavis.edu
Fax: +1 530-752-8995
Tel: +1 530-752-691

Abstract

The iron(II) diaryl FeAr′2 (1) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) reacts cleanly with O2 or CO to afford the monomeric, two-coordinate bis(aryloxide) Fe(OAr′)2 (2) or the η2-acyl–carbonyl complex (η2-Ar′C[double bond, length as m-dash]O)2Fe(CO)2 (3) viaoxygen or CO insertion into the Fe–C bonds; complex 2 has a strictly linear geometry and shows remarkable resistance to O2oxidation.

Graphical abstract: Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide

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Article information

DOI
https://doi.org/10.1039/B912312A
Article type
Communication
Submitted
23 六月 2009
Accepted
24 七月 2009
First published
17 八月 2009

Chem. Commun., 2009, 5543-5545

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Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide

C. Ni and P. P. Power, Chem. Commun., 2009, 5543 DOI: 10.1039/B912312A

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