Issue 13, 2022

Cellulose-assisted electrodeposition of zinc for morphological control in battery metal recycling

Abstract

Cellulose nanofibers (CNFs) are demonstrated as an effective tool for converting electrodeposits into more easily detachable dendritic deposits useful in recycling zinc ion batteries via electrowinning. The incorporation of CNFs at concentrations ranging from 0.01 to 0.5 g L−1 revealed a progressively increasing and more extensive formation of a nacre-like dendritic zinc structure that did not form in its absence. Increasing the CNF concentrations to 0.5 g L−1 resulted in the most extensive formation of dendritic structures. The explanation for the observed phenomenon is the ability of CNFs to strongly interact with metal ions, i.e., restricting the mobility of the ions towards the electrowinning electrode. At the highest concentration of CNFs (0.5 g L−1), in combination with the lowest current density (150 A m−2), electrodeposition was limited to the extent that formed deposits were almost non-existent. The electrodeposition in the presence of CNFs was further evaluated at different temperatures of 20, 40 and 60 °C. The dendritic formation was increasingly suppressed with increasing temperatures, and at a temperature of 60 °C, the electrodeposited morphologies could not be differentiated from the morphologies formed in the absence of the cellulose. The results stemmed from a greater mobility of the metal ions at elevated temperatures, while at the same time suggests an inability of the CNF to strongly associate the metal ions at elevated temperatures. High-pressure blasted titanium electrodes were used as a reference material for accurate comparisons, and electron microscopy (FE-SEM) and X-ray diffraction were used to characterize zinc morphologies and crystallite sizes, respectively. This article reports the first investigation on how dispersions of highly crystalline cellulose nanofibers can be used as a renewable and functional additive during the recycling of battery metal ions. The metal-ion/cellulose interactions may also allow for structural control in electrodeposition of other metal ions.

Graphical abstract: Cellulose-assisted electrodeposition of zinc for morphological control in battery metal recycling

Associated articles

Supplementary files

Article information

Article type
Paper
Submitted
03 3月 2022
Accepted
13 4月 2022
First published
15 4月 2022
This article is Open Access
Creative Commons BY-NC license

Mater. Adv., 2022,3, 5304-5314

Cellulose-assisted electrodeposition of zinc for morphological control in battery metal recycling

B. W. Hoogendoorn, M. Parra, A. J. Capezza, Y. Li, K. Forsberg, X. Xiao and R. T. Olsson, Mater. Adv., 2022, 3, 5304 DOI: 10.1039/D2MA00249C

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements