Issue 4, 2017

Quantifying the efficiency of CO2 capture by Lewis pairs

Abstract

A microfluidic strategy has been used for the time- and labour-efficient evaluation of the relative efficiency and thermodynamic parameters of CO2 binding by three Lewis acid/base combinations, where efficiency is based on the amount of CO2 taken up per binding unit in solution. Neither tBu3P nor B(C6F5)3 were independently effective at CO2 capture, and the combination of the imidazolin-2-ylidenamino-substituted phosphine (NIiPr)3P and B(C6F5)3 was equally ineffective. Nonetheless, an archetypal frustrated Lewis pair (FLP) comprised of tBu3P and B(C6F5)3 was shown to bind CO2 more efficiently than either the FLP derived from tetramethylpiperidine (TMP) and B(C6F5)3 or the highly basic phosphine (NIiPr)3P. Moreover, the proposed microfluidic platform was used to elucidate the thermodynamic parameters for these reactions.

Graphical abstract: Quantifying the efficiency of CO2 capture by Lewis pairs

Supplementary files

Article information

Article type
Edge Article
Submitted
21 12月 2016
Accepted
17 2月 2017
First published
20 2月 2017
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2017,8, 3270-3275

Quantifying the efficiency of CO2 capture by Lewis pairs

J. J. Chi, T. C. Johnstone, D. Voicu, P. Mehlmann, F. Dielmann, E. Kumacheva and D. W. Stephan, Chem. Sci., 2017, 8, 3270 DOI: 10.1039/C6SC05607E

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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