Issue 45, 2013

A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Abstract

Solvothermal reaction of a dendritic hexacarboxylic acid with Tb(NO3)3·6H2O afforded a mesoporous lanthanide–organic framework (UTSA-61) whose single-crystal X-ray structure was characterized to have octahedral cages of 2.4 nm in diameter. This mesoporous MOF not only exhibits novel hey topology, but also maintains permanent porosity as shown in its N2, H2, CO2 and CH4 gas sorption isotherms.

Graphical abstract: A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Supplementary files

Article information

Article type
Communication
Submitted
08 6月 2013
Accepted
29 7月 2013
First published
31 7月 2013

CrystEngComm, 2013,15, 9328-9331

A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Y. He, H. Furukawa, C. Wu, M. O'Keeffe and B. Chen, CrystEngComm, 2013, 15, 9328 DOI: 10.1039/C3CE41062E

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