The two-electron reduced mixed-valence polyoxometalate [GeV14O40]8− presents an unusual paramagnetic behaviour as a consequence of the partial trapping of these electrons. The effect of applying an electric field is that of inducing antiferromagnetic coupling between the two delocalized electronic spins.
![Graphical abstract: Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−](/zh-hans/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CC44859B&imageInfo.ImageIdentifier.Year=2013)
S. Cardona-Serra, J. M. Clemente-Juan, A. Gaita-Ariño, N. Suaud, O. Svoboda and E. Coronado, Chem. Commun., 2013, 49, 9621 DOI: 10.1039/C3CC44859B
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