Cross Reference Logo
Citations to this article as recorded by CrossRef and RSC Journals (317 citations).

Strong metal–borane interactions in low-valent cyclopentadienyl rhodium complexes
Maxime Boudjelel, Sonia Mallet-Ladeira, Ghenwa Bouhadir and Didier Bourissou
Chem. Commun., 2019, 55, 12837
DOI: 10.1039/C9CC06639J

Synthesis, structure and palladium coordination of ambiphilic, pyridine- and phosphine-tethered N-boryl imine ligands
Fabio Lorenzini, Pierre-Louis Lagueux-Tremblay, Laure V. Kayser, Ethan Anderson and Bruce A. Arndtsen
Dalton Trans., 2019, 48, 5766
DOI: 10.1039/C8DT05100C

Chemo-selective Stille-type coupling of acyl-chlorides upon phosphine-borane Au(i) catalysis
Nereida Hidalgo, Arnaud Le Gac, Sonia Mallet-Ladeira, Ghenwa Bouhadir and Didier Bourissou
Chem. Sci., 2024, 15, 5187
DOI: 10.1039/D3SC06193K

Ambiphilic boryl groups in a neutral Ni(ii) complex: a new activation mode of H2
Pablo Ríos, Javier Borge, Francisco Fernández de Córdova, Giuseppe Sciortino, Agustí Lledós and Amor Rodríguez
Chem. Sci., 2021, 12, 2540
DOI: 10.1039/D0SC06014C

A diamidinatogermylene as a Z-type ligand in a nickel(0) complex
Zhongtao Feng, Yixiao Jiang, Huapeng Ruan, Yue Zhao, Gengwen Tan, Li Zhang and Xinping Wang
Dalton Trans., 2019, 48, 14975
DOI: 10.1039/C9DT03803E

A sterically congested 1,2-diphosphino-1′-boryl-ferrocene: synthesis, characterization and coordination to platinum
Emmanuel Lerayer, Patrice Renaut, Julien Roger, Nadine Pirio, Hélène Cattey, Paul Fleurat-Lessard, Maxime Boudjelel, Stéphane Massou, Ghenwa Bouhadir, Didier Bourissou and Jean-Cyrille Hierso
Dalton Trans., 2019, 48, 11191
DOI: 10.1039/C9DT01921A

Reactions of an anionic chelate phosphane/borata-alkene ligand with [Rh(nbd)Cl]2, [Rh(CO)2Cl]2 and [Ir(cod)Cl]2
Kohei Watanabe, Atsushi Ueno, Xin Tao, Karel Škoch, Xiaoming Jie, Sergei Vagin, Bernhard Rieger, Constantin G. Daniliuc, Matthias C. Letzel, Gerald Kehr and Gerhard Erker
Chem. Sci., 2020, 11, 7349
DOI: 10.1039/D0SC02223C

Small molecule activation with bimetallic systems: a landscape of cooperative reactivity
Miquel Navarro, Juan José Moreno, Marina Pérez-Jiménez and Jesús Campos
Chem. Commun., 2022, 58, 11220
DOI: 10.1039/D2CC04296G

Expanding the allyl analogy: accessing η3-P,B,P diphosphinoborane complexes of group 10
Marcus W. Drover and Jonas C. Peters
Dalton Trans., 2018, 47, 3733
DOI: 10.1039/C8DT00058A

In defence of oxidation states
Nicholas C. Norman and Paul G. Pringle
Dalton Trans., 2022, 51, 400
DOI: 10.1039/D0DT03914D

Zero-valent isocyanides of nickel, palladium and platinum as transition metal σ-type Lewis bases
Brandon R. Barnett and Joshua S. Figueroa
Chem. Commun., 2016, 52, 13829
DOI: 10.1039/C6CC07863J

A tetranuclear lanthanum–nickel hydrido complex supported by an arene-anchored bis(phosphinomethylamido) ligand
Xiuyan He, Changjiang Wu, Dongjing Hong, Huayi Fang and Peng Cui
Chem. Commun., 2026, 62, 3807
DOI: 10.1039/D5CC06726J

2-Alkylphosphino-1-boraadamantanes
Kurt F. Hoffmann, Rayni P. Noriega, Paul D. Boyle and Marcus W. Drover
Chem. Commun., 2024, 60, 9222
DOI: 10.1039/D4CC02665A

Synthesis and reactions of a zirconium naphthalene complex bearing a tetraanionic C-capped triaryloxide ligand
Yusuke Nakanishi, Yutaka Ishida and Hiroyuki Kawaguchi
Dalton Trans., 2016, 45, 15879
DOI: 10.1039/C6DT01848C

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts
Matthew R. Elsby and R. Tom Baker
Chem. Soc. Rev., 2020, 49, 8933
DOI: 10.1039/D0CS00509F

Understanding the role of frustrated Lewis pairs as ligands in transition metal-catalyzed reactions
Jorge Juan Cabrera-Trujillo and Israel Fernández
Dalton Trans., 2020, 49, 3129
DOI: 10.1039/C9DT04806E

Non-spectator behavior of a neutral phosphine ligand driven by a redox-active boron cluster
Jared R. Riffle, Cash L. Jowers, Sarah Luna, Mark D. Smith and Dmitry V. Peryshkov
Chem. Sci., 2025, 16, 15997
DOI: 10.1039/D5SC04058B

A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification
Emmanuel Lerayer, Patrice Renaut, Julien Roger, Nadine Pirio, Hélène Cattey, Charles H. Devillers, Dominique Lucas and Jean-Cyrille Hierso
Chem. Commun., 2017, 53, 6017
DOI: 10.1039/C7CC02469J

Synthesis and properties of heterobimetallic rhodium complexes featuring LiI, CuI or ZnII as a Lewis acidic metalloligand
Patrick Steinhoff, Ralf Steinbock, Anna Friedrich, Benjamin G. Schieweck, Christopher Cremer, Khai-Nghi Truong and Michael E. Tauchert
Dalton Trans., 2018, 47, 10439
DOI: 10.1039/C8DT01267A

Cationic and neutral ruthenium(ii) complexes bearing silyl-phosphines: synthesis, structures, and catalytic studies in selective hydroboration of carbonyl compounds
Amiya Kumar Sahoo, Rageshree Dash, Suraj Kumar Agrawalla, Chandra Shekhar Purohit and Adinarayana Doddi
Dalton Trans., 2025, 54, 4312
DOI: 10.1039/D4DT03550J

Ligand-enforced intimacy between a gold cation and a carbenium ion: impact on stability and reactivity
Elishua D. Litle, Lewis C. Wilkins and François P. Gabbaï
Chem. Sci., 2021, 12, 3929
DOI: 10.1039/D0SC05777K

Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH3, N2H4, H2O, H2)
Maximilian Auer, Janina Bolten, Klaus Eichele, Hartmut Schubert, Christian P. Sindlinger and Lars Wesemann
Chem. Sci., 2023, 14, 514
DOI: 10.1039/D2SC05620H

A cationic gold-fluorenyl complex with a dative Au → C+ bond: synthesis, structure, and carbophilic reactivity
Elishua D. Litle and François P. Gabbaï
Chem. Commun., 2023, 59, 603
DOI: 10.1039/D2CC05436A

Isolation of ligand-centered borocations in molybdenum complexes containing a triaminoborane-bridged diphosphorus ligand
Kyounghoon Lee, Chan Woo Kim, Jimmy L. Buckley, Bess Vlaisavljevich and Scott R. Daly
Dalton Trans., 2019, 48, 3777
DOI: 10.1039/C9DT00733D

Heterobimetallic μ2-carbido complexes of platinum and tungsten
Liam K. Burt and Anthony F. Hill
Dalton Trans., 2020, 49, 8143
DOI: 10.1039/D0DT01617A

L/Z-ligand type amphoterism of an acridinium unit
Elishua D. Litle, Shantabh Bedajna and François P. Gabbaï
Chem. Sci., 2025, 16, 10852
DOI: 10.1039/D5SC00965K

Ligand K-edge XAS, DFT, and TDDFT analysis of pincer linker variations in Rh(i) PNP complexes: reactivity insights from electronic structure
Kyounghoon Lee, Haochuan Wei, Anastasia V. Blake, Courtney M. Donahue, Jason M. Keith and Scott R. Daly
Dalton Trans., 2016, 45, 9774
DOI: 10.1039/C6DT00200E

A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds
Lei Ma, Xiaowei Pan, Dongjing Hong, Huayi Fang and Peng Cui
Chem. Commun., 2024, 60, 4222
DOI: 10.1039/D4CC00547C

The effect of auxiliary ligand on the mechanism and reactivity: DFT study on H2 activation by Lewis acid–transition metal complex (tris(phosphino)borane)Fe(L)
Jianyu Zhang, Jiasheng Lin, Yinwu Li, Youxiang Shao, Xiao Huang, Cunyuan Zhao and Zhuofeng Ke
Catal. Sci. Technol., 2017, 7, 4866
DOI: 10.1039/C7CY01217A

Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site
Danny Schuhknecht, Florian Ritter and Michael E. Tauchert
Chem. Commun., 2016, 52, 11823
DOI: 10.1039/C6CC07079E

Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal–metal bonds
Jun Takaya, Mayuko Hoshino, Kanako Ueki, Narumasa Saito and Nobuharu Iwasawa
Dalton Trans., 2019, 48, 14606
DOI: 10.1039/C9DT03443A

Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes
Mark R. St.-J. Foreman, Anthony F. Hill, Chenxi Ma, Never Tshabang and Andrew J. P. White
Dalton Trans., 2019, 48, 209
DOI: 10.1039/C8DT04278K

Bimetallic Al–M complexes derived from low-valent aluminium sources (M = s-/p-block metal)
Martyn P. Coles
Chem. Commun., 2025, 61, 15125
DOI: 10.1039/D5CC03764F

A comparison of the coordination behaviour of R2PCH2BMe2 (R = Me vs. Ph) ambiphilic ligands with late transition metals
Katia M. Paskaruk, David J. H. Emslie and James F. Britten
Dalton Trans., 2023, 52, 15712
DOI: 10.1039/D3DT02538A

Heterobimetallic ruthenium–zinc complexes with bulky N-heterocyclic carbenes: syntheses, structures and reactivity
Maialen Espinal-Viguri, Victor Varela-Izquierdo, Fedor M. Miloserdov, Ian M. Riddlestone, Mary F. Mahon and Michael K. Whittlesey
Dalton Trans., 2019, 48, 4176
DOI: 10.1039/C8DT05023F

Elucidating metal hydride reactivity using late transition metal boryl and borane hydrides: 2c–2e terminal hydride, 3c–2e bridging hydride, and 3c–4e bridging hydride
Yinwu Li, Jiahao Liu, Cheng Hou, Youxiang Shao, Ling-Bo Qu, Cunyuan Zhao and Zhuofeng Ke
Catal. Sci. Technol., 2018, 8, 3395
DOI: 10.1039/C8CY00766G

Cooperative borane activation by tuning hemilability of different Os-κ2-N,Se-chelated complexes
Faneesha Assanar, Sourav Gayen, Deepak Kumar Patel, Thalappil Pradeep and Sundargopal Ghosh
Chem. Sci., 2026, 17, 3129
DOI: 10.1039/D5SC06346A

Facile reactions of gold(i) complexes with tri(tert-butyl)azadiboriridine
Rong Shang, Souta Saito, J. Oscar C. Jimenez-Halla and Yohsuke Yamamoto
Dalton Trans., 2018, 47, 5181
DOI: 10.1039/C8DT00697K

Dihydrobis(methimazolyl)borato complexes of ruthenium and osmium
Mark R. St.-J. Foreman, Chenxi Ma, Anthony F. Hill, Natalie E. Otten, Manab Sharma, Never Tshabang and Jas S. Ward
Dalton Trans., 2017, 46, 14957
DOI: 10.1039/C7DT02420G

Phosphinoamido ligand supported heterobimetallic rare-earth metal–palladium complexes: versatile structures and redox reactivities
Jun Du, Xiuyan He, Dongjing Hong, Shuangliu Zhou, Huayi Fang and Peng Cui
Dalton Trans., 2022, 51, 8777
DOI: 10.1039/D2DT01084D

Ligand exchange of tris(2,4-di-tert-butylphenyl) phosphite: a practical and efficient route to organo gold(i) complexes
David Vesseur, Shuo Li, Sonia Mallet-Ladeira and Didier Bourissou
Chem. Commun., 2025, 61, 18717
DOI: 10.1039/D5CC05744B

Synthesis and reactivity of phosphine borohydride compounds
Ramaraj Ayyappan, Yannick Coppel, Laure Vendier, Sundargopal Ghosh, Sylviane Sabo-Etienne and Sébastien Bontemps
Chem. Commun., 2021, 57, 375
DOI: 10.1039/D0CC07072F

Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation
Hajime Kameo, Akihiro Mushiake, Tomohito Isasa, Hiroyuki Matsuzaka and Didier Bourissou
Chem. Commun., 2021, 57, 5004
DOI: 10.1039/D1CC01392K

Triaminoborane-bridged diphosphine complexes with Ni and Pd: coordination chemistry, structures, and ligand-centered reactivity
Kyounghoon Lee, Courtney M. Donahue and Scott R. Daly
Dalton Trans., 2017, 46, 9394
DOI: 10.1039/C7DT02144E

Unsaturated vicinal frustrated phosphane/borane Lewis pairs as ligands in gold(i) chemistry
Atsushi Ueno, Kohei Watanabe, Constantin G. Daniliuc, Gerald Kehr and Gerhard Erker
Chem. Commun., 2019, 55, 4367
DOI: 10.1039/C9CC01136F

Diferrocenylmercury diphosphine diastereomers with unique geometries:trans-chelation at Pd(ii) with short Hg(ii)⋯Pd(ii) contacts
Alain C. Tagne Kuate, Roger A. Lalancette, Thomas Bannenberg, Matthias Tamm and Frieder Jäkle
Dalton Trans., 2019, 48, 13430
DOI: 10.1039/C9DT02728A

Heterobimetallic Pd(0) complexes with Pd→Ln (Ln = Sc, Y, Yb, Lu) dative bonds: rare-earth metal-dominated frustrated Lewis pair-like reactivity
Jun Du, Yanan Zhang, Zeming Huang, Shuangliu Zhou, Huayi Fang and Peng Cui
Dalton Trans., 2020, 49, 12311
DOI: 10.1039/D0DT02708A

Bis(1-bora-4-phosphorinane) ring closure at Cp*M (M = Fe, Co) complexes
Joseph A. Zurakowski, Brady J. H. Austen, Kasey R. Brown and Marcus W. Drover
Chem. Commun., 2022, 58, 2500
DOI: 10.1039/D1CC07060F

Preparation and reactivity of rhodium and iridium complexes containing a methylborohydride based unit supported by two 7-azaindolyl heterocycles
Rosenildo Correa Da Costa, Benjamin W. Rawe, Nikolaos Tsoureas, Mairi F. Haddow, Hazel A. Sparkes, Graham J. Tizzard, Simon J. Coles and Gareth R. Owen
Dalton Trans., 2018, 47, 11047
DOI: 10.1039/C8DT02311E

Primary and secondary coordination sphere Lewis acid interactions in β-phosphinoethylborane-ligated rhodium and iridium complexes
Brian R. Nichols, Jeffrey L. Petersen, Brian S. Dolinar and Brian V. Popp
New J. Chem., 2025, 49, 14073
DOI: 10.1039/D5NJ01429H

Metal–ligand–Lewis acid multi-cooperative catalysis: a step forward in the Conia-ene reaction
Arnaud Clerc, Enrico Marelli, Nicolas Adet, Julien Monot, Blanca Martín-Vaca and Didier Bourissou
Chem. Sci., 2021, 12, 435
DOI: 10.1039/D0SC05036A

Synthesis and characterization of heterotrimetallic Mg–Ni–Mg complexes with amidinato ligands
Rongping Zhang, Yanping Cai and Xin Xu
Dalton Trans., 2025, 54, 3437
DOI: 10.1039/D4DT03495C

Synthesis and reactivity of heterometallic complexes containing Mg- or Zn-metalloligands
Yanping Cai, Shengjie Jiang, Liqiu Dong and Xin Xu
Dalton Trans., 2022, 51, 3817
DOI: 10.1039/D1DT04117G

Functional group migrations between boron and metal centres within transition metal–borane and –boryl complexes and cleavage of H–H, E–H and E–E′ bonds
Gareth R. Owen
Chem. Commun., 2016, 52, 10712
DOI: 10.1039/C6CC03817D

Dinuclear gold catalysis
Wenliang Wang, Cheng-Long Ji, Kai Liu, Chuan-Gang Zhao, Weipeng Li and Jin Xie
Chem. Soc. Rev., 2021, 50, 1874
DOI: 10.1039/D0CS00254B

Reactivity of gold and copper acetylide with a secondary borane
Ragene A. Thornton, Kirk French, Kevin Shuford and Caleb D. Martin
Chem. Commun., 2026, 62, 1193
DOI: 10.1039/D5CC06957B

Tunable carbocation-based redox active ambiphilic ligands: synthesis, coordination and characterization
Liangyong Mei, José M. Veleta, Jan Bloch, Hannah J. Goodman, Dominic Pierce-Navarro, Alejandro Villalobos and Thomas L. Gianetti
Dalton Trans., 2020, 49, 16095
DOI: 10.1039/D0DT00419G

A catalytic collaboration: pairing transition metals and Lewis acids for applications in organic synthesis
A. Dina Dilinaer, Gabriel J. Jobin and Marcus W. Drover
Dalton Trans., 2024, 53, 13298
DOI: 10.1039/D4DT01550A

Beyond phosphorus: synthesis, reactivity, coordination behaviour and catalytic properties of 1,1′-bis(diphenylstibino)ferrocene
Jiří Schulz, Jakub Antala, Ivana Císařová and Petr Štěpnička
Dalton Trans., 2023, 52, 1198
DOI: 10.1039/D2DT03770J

Relative hemilabilities of H2B(az)2 (az = pyrazolyl, dimethylpyrazolyl, methimazolyl) chelates in the complexes [M(η-C3H5)(CO)2{H2B(az)2}] (M = Mo, W)
Robyn J. Abernethy, Mark R. St.-J. Foreman, Anthony F. Hill, Matthew K. Smith and Anthony C. Willis
Dalton Trans., 2020, 49, 781
DOI: 10.1039/C9DT03744F

Platinum complexes of a boron-rich diphosphine ligand
Marcus W. Drover, Eric G. Bowes, Maeve C. Dufour and Lindsay A. Lesperance-Nantau
Dalton Trans., 2020, 49, 16312
DOI: 10.1039/D0DT00963F

Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(i) metal-only Lewis pair
Nereida Hidalgo, Celia Maya and Jesús Campos
Chem. Commun., 2019, 55, 8812
DOI: 10.1039/C9CC03008E

An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides
Srobona Sen and François P. Gabbaï
Chem. Commun., 2017, 53, 13356
DOI: 10.1039/C7CC06065C

Metal–ligand cooperation at tethered π-ligands
Dide G. A. Verhoeven and Marc-Etienne Moret
Dalton Trans., 2016, 45, 15762
DOI: 10.1039/C6DT02184K

A neutral, acyclic, borataalkene-like ligand for group 11 metals: L- and Z-type ligands side by side
Felix Krämer, Michael Radius, Helga Berberich, Israel Fernández and Frank Breher
Chem. Commun., 2022, 58, 3905
DOI: 10.1039/D2CC00199C

Borataalkenes, boraalkenes, and the η2-B,C coordination mode in coordination chemistry and catalysis
Maxwell Eaton, Yuanzhe Zhang and Shih-Yuan Liu
Chem. Soc. Rev., 2024, 53, 1915
DOI: 10.1039/D3CS00730H

Antimony centre in three different roles: does donor strength or acceptor ability determine the bonding pattern?
Richard Chlebík, Csilla Fekete, Roman Jambor, Aleš Růžička, Zoltán Benkő and Libor Dostál
Dalton Trans., 2024, 53, 17721
DOI: 10.1039/D4DT02787F

Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands
Patrick Steinhoff, Melanie Paul, Julian P. Schroers and Michael E. Tauchert
Dalton Trans., 2019, 48, 1017
DOI: 10.1039/C8DT03777A

Isolation and reactivity of a gold(i) hydroxytrifluoroborate complex stabilized by anion-π+ interactions
Jiliang Zhou, Elishua D. Litle and François P. Gabbaï
Chem. Commun., 2021, 57, 10154
DOI: 10.1039/D1CC04105C

Design of boron-decorated bimetallic iron complexes related to the active site of [FeFe]-hydrogenases and reactivity with hydride donors
Ines Bennour, Victor Monnot, Philippe Schollhammer and Lucile Chatelain
Dalton Trans., 2026, 55, 1915
DOI: 10.1039/D5DT02885J

New cationic coinage metal complexes featuring silyl group functionalized phosphine: syntheses, structures and catalytic studies in alkyne–azide cycloaddition reactions
Amiya Kumar Sahoo, Ashish Kumar Sahoo, Bhagyashree Das, Subhra Jyoti Panda, Chandra Shekhar Purohit and Adinarayana Doddi
Dalton Trans., 2023, 52, 15549
DOI: 10.1039/D3DT01692G

Access to a pair of ambiphilic phosphine–borane regioisomers by rhodium-catalyzed hydroboration
Brian R. Nichols, Novruz G. Akhmedov, Jeffrey L. Petersen and Brian V. Popp
Dalton Trans., 2018, 47, 8456
DOI: 10.1039/C8DT01467A

1,1-Phosphaboration of CC and CC bonds at gold
Cyril A. Theulier, Yago García-Rodeja, Nathalie Saffon-Merceron, Karinne Miqueu, Ghenwa Bouhadir and Didier Bourissou
Chem. Commun., 2021, 57, 347
DOI: 10.1039/D0CC06978G

Coordination chemistry and structural rearrangements of the Me2PCH2AlMe2ambiphilic ligand
Katarina Paskaruk, David J. H. Emslie and James F. Britten
Dalton Trans., 2022, 51, 15040
DOI: 10.1039/D2DT02519A

Palladium(0) complexes of diferrocenylmercury diphosphines: synthesis, X-ray structure analyses, catalytic isomerization, and C–Cl bond activation
Alain C. Tagne Kuate, Roger. A. Lalancette, Dirk Bockfeld, Matthias Tamm and Frieder Jäkle
Dalton Trans., 2021, 50, 4512
DOI: 10.1039/D1DT00641J

Metal–metal multiple bond formation induced by σ-acceptor Lewis acid ligands
Shin Takemoto, Kaname Yoshii, Takahiro Yamano, Akihiro Tsurusaki and Hiroyuki Matsuzaka
Chem. Commun., 2021, 57, 923
DOI: 10.1039/D0CC07278H

The cooperative role of innocent ligand in N-heterocyclic carbene manganese catalyzed carbon dioxide hydrogenation
Yaru Jing, Jiahao Liu, Zongren Ye, Jiaqi Su, Yan Liu and Zhuofeng Ke
Catal. Sci. Technol., 2021, 11, 7189
DOI: 10.1039/D1CY01211H

Synthesis and reactivity of PC(sp3)P-pincer iridium complexes bearing a diborylmethyl anion
Masamichi Kishino, Satoko Takaoka, Yuki Shibutani, Shuhei Kusumoto and Kyoko Nozaki
Dalton Trans., 2022, 51, 5009
DOI: 10.1039/D2DT00513A

Facile synthesis and utilization of bis(o-phosphinophenyl)zinc as isolable PZnP-pincer ligands enabled by boron–zinc double transmetallation
Kazuishi Fukuda, Takuma Harada, Nobuharu Iwasawa and Jun Takaya
Dalton Trans., 2022, 51, 7035
DOI: 10.1039/D2DT01222G

5-Mercaptotetrazolyl-derived metallaboratranes
Anthony F. Hill, Torsten Schwich and Yaoyao Xiong
Dalton Trans., 2019, 48, 2367
DOI: 10.1039/C8DT05036H

Methimazolyl based diptych bicyclo-[3.3.0]-ruthenaboratranes
Chenxi Ma and Anthony F. Hill
Dalton Trans., 2019, 48, 1976
DOI: 10.1039/C8DT04813D

Ruthenium–NHC complex-catalyzed P(iii)-directed C–H borylation of arylphosphines
Jompol Thongpaen, Romane Manguin, Tanakorn Kittikool, Aurèle Camy, Thierry Roisnel, Vincent Dorcet, Sirilata Yotphan, Yves Canac, Marc Mauduit and Olivier Baslé
Chem. Commun., 2022, 58, 12082
DOI: 10.1039/D2CC03909E

Can an alkalide act as a perfect Lewis base?
Amlan J. Kalita, Siddhartha K. Purkayastha, Kangkan Sarmah and Ankur K. Guha
Phys. Chem. Chem. Phys., 2022, 24, 18144
DOI: 10.1039/D2CP02800J

Catalysis using transition metal complexes featuring main group metal and metalloid compounds as supporting ligands
Jun Takaya
Chem. Sci., 2021, 12, 1964
DOI: 10.1039/D0SC04238B

Heterobimetallic scandium–group 10 metal complexes with LM → Sc (LM = Ni, Pd, Pt) dative bonds
Peng Cui, Chunyan Xiong, Jun Du, Zeming Huang, Sijun Xie, Hua Wang, Shuangliu Zhou, Huayi Fang and Shaowu Wang
Dalton Trans., 2020, 49, 124
DOI: 10.1039/C9DT04369A

Trinuclear anionic gold clusters bridged by dialkylsilylene and dialkylgermylene
Yinhuan Li, Guorong Zhen, Lu Huang, Rong Zhang, Liliang Wang, Fan Qi, Mitsuo Kira and Zhifang Li
Chem. Commun., 2022, 58, 6705
DOI: 10.1039/D2CC02054H

Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes
James T. Moore, Nicholas E. Smith and Connie C. Lu
Dalton Trans., 2017, 46, 5689
DOI: 10.1039/C6DT04769F

Exploring the potential role of heavy pnictogen elements in ligand design for new metal-ligand cooperative chemistry
W. M. Hollingsworth and E. A. Hill
Journal of Coordination Chemistry, 2022, 75, 1436
DOI: 10.1080/00958972.2022.2124863

A Bimetallic Nickel–Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride
Ryan C. Cammarota, Matthew V. Vollmer, Jing Xie, Jingyun Ye, John C. Linehan, Samantha A. Burgess, Aaron M. Appel, Laura Gagliardi and Connie C. Lu
J. Am. Chem. Soc., 2017, 139, 14244
DOI: 10.1021/jacs.7b07911

Rare-Earth Metalloligands for Low-Valent Cobalt Complexes: Fine Electronic Tuning via Co→RE Dative Interactions
Xiuyan He, Xiaowei Pan, Chunyan Xiong, Yun Zhang, Dongjing Hong, Huayi Fang and Peng Cui
Inorg. Chem., 2024, 63, 8155
DOI: 10.1021/acs.inorgchem.4c00367

Ligand-Centered Borenium Reactivity in Triaminoborane-Bridged Diphosphine Complexes
Kyounghoon Lee, Clara Kirkvold, Bess Vlaisavljevich and Scott R. Daly
Inorg. Chem., 2018, 57, 13188
DOI: 10.1021/acs.inorgchem.8b01601

Insight into the MOtBu (M=Na, K)‐Mediated Dehydrogenation of Dimethylamine‐Borane and Transfer Hydrogenation of Nitriles to Primary Amines
Deep Chowdhury, Rahul Sutradhar, Ankan Paul and Arup Mukherjee
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400942

Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms
Takashi Komuro, Yumiko Nakajima, Jun Takaya and Hisako Hashimoto
Coordination Chemistry Reviews, 2022, 473, 214837
DOI: 10.1016/j.ccr.2022.214837

Metal→Carbon Dative Bonding
Elishua D. Litle and François P. Gabbaï
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202201841

Ultrasonic green synthesis of an Ag/CP nanocomposite for enhanced photodegradation effectiveness
Hai Ning Chang, Suo Xia Hou, Zeng Chuan Hao and Guang Hua Cui
Ultrasonics Sonochemistry, 2018, 40, 1039
DOI: 10.1016/j.ultsonch.2017.09.004

Dehydrogenative Double C−H Bond Activation in a Germylene‐Rhodium Complex**
Sonia Bajo, María M. Alcaide, Joaquín López‐Serrano and Jesús Campos
Chemistry A European J, 2021, 27, 16422
DOI: 10.1002/chem.202102529

Comparing the Acidity of (R3P)2BH-Based Donor Groups in Iridium Pincer Complexes
Leon Maser, Christian Schneider, Lukas Alig and Robert Langer
Inorganics, 2019, 7, 61
DOI: 10.3390/inorganics7050061

Frustrated Lewis Pair Chelation in the p‐Block
Brandon L. Frenette and Eric Rivard
Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302332

Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination
Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka and Didier Bourissou
Angewandte Chemie, 2019, 131, 18959
DOI: 10.1002/ange.201909675

Reactivity of ruthenium complexes towards organogallium reagents: Gallium as a Z-type ligand or as a gallate counterion
Gabriela Sanchez-Lecuona, Mayra C. Vazquez-Nunez, Bruno Donnadieu, Miguel A. Muñoz-Hernández and Virginia Montiel-Palma
Polyhedron, 2024, 247, 116703
DOI: 10.1016/j.poly.2023.116703

Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation
Taichi Nakamura, Katsunori Suzuki and Makoto Yamashita
J. Am. Chem. Soc., 2017, 139, 17763
DOI: 10.1021/jacs.7b11127

A Borane Platinum Complex Undergoing Reversible Hydride Migration in Solution
Abdollah Neshat, Hamid R. Shahsavari, Piero Mastrorilli, Stefano Todisco, Mohsen Golbon Haghighi and Behrouz Notash
Inorg. Chem., 2018, 57, 1398
DOI: 10.1021/acs.inorgchem.7b02807

Cooperative C–H Bond Activation by a Low-Spin d6 Iron–Aluminum Complex
Nikolaus Gorgas, Andrew J. P. White and Mark R. Crimmin
J. Am. Chem. Soc., 2022, 144, 8770
DOI: 10.1021/jacs.2c02662

Synthesis, Structures, and Properties of Terphenyl Diamido Complexes of Cobalt(I)
Suiho Kobayashi, Yuka Yamada, Tsubasa Hatanaka, Motohiro Nakano and Yasuhiro Funahashi
Eur J Inorg Chem, 2025, 28
DOI: 10.1002/ejic.202400834

Cooperative Activation of CO and Pyridine by an Aluminum(I) Complex Ligated with a Silylene–Borane Ligand
Jinghuang Lv, Xiao Fang, Fanshu Cao and Zhenbo Mo
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202512084

T-Shaped Gold→Stiborane Complexes as Carbophilic Catalysts: Influence of the Peripheral Substituents
Srobona Sen, Iou-Sheng Ke and François P. Gabbaï
Organometallics, 2017, 36, 4224
DOI: 10.1021/acs.organomet.7b00654

Stabilized Carbenium Ions as Latent, Z‐type Ligands
Lewis C. Wilkins, Youngmin Kim, Elishua D. Litle and François P. Gabbaï
Angew Chem Int Ed, 2019, 58, 18266
DOI: 10.1002/anie.201911662

Metal/Non‐Metal Catalyzed Activation of Organic Nitriles
Suman Das, Jyotirmoy Maity and Tarun K. Panda
The Chemical Record, 2022, 22
DOI: 10.1002/tcr.202200192

Synthesis, Structure, and Reactivity of Ruthenium‐Indane Complexes with Diphosphine Ligand
Masumi Itazaki, Natsumi Kitani, Yukako Dobashi, Kento Okabayashi, Hiroshi Nakazawa and Toshiyuki Moriuchi
Eur J Inorg Chem, 2024, 27
DOI: 10.1002/ejic.202400415

(Acetamide-κO){2,2′,2′′-boranetriyltris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ4 B,S,S′,S′′}copper(I) trifluoromethanesulfonate chloroform disolvate
Stefan Holler, Ferdinand Belaj and Nadia C. Mösch-Zanetti
IUCrData, 2018, 3
DOI: 10.1107/S2414314618000378

Selective Double Addition Reaction of an E‒H Bond (E = Si, B) to a C≡N Triple Bond of Organonitriles
Masumi Itazaki and Hiroshi Nakazawa
Molecules, 2018, 23, 2769
DOI: 10.3390/molecules23112769

Molecular Orbital Insights of Transition Metal-Stabilized Carbocations
Hannah Goodman, Liangyong Mei and Thomas L. Gianetti
Front. Chem., 2019, 7
DOI: 10.3389/fchem.2019.00365

Diferrocenylmercury‐Bridged Diphosphine: A Chiral, Ambiphilic, and Redox‐Active Bidentate Ligand
Alain C. Tagne Kuate, Roger A. Lalancette, Thomas Bannenberg and Frieder Jäkle
Angewandte Chemie, 2018, 130, 6662
DOI: 10.1002/ange.201803086

Bonding and Reactivity of a Pair of Neutral and Cationic Heterobimetallic RuZn2 Complexes
Fedor M. Miloserdov, Anne-Frédérique Pécharman, Lia Sotorrios, Nasir A. Rajabi, John P. Lowe, Stuart A. Macgregor, Mary F. Mahon and Michael K. Whittlesey
Inorg. Chem., 2021, 60, 16256
DOI: 10.1021/acs.inorgchem.1c02072

Coordinatively Unsaturated Metallates of Cobalt(II), Nickel(II), and Zinc(II) Guarded by a Rigid and Narrow Void
Christopher D. Hastings, Lucy S. X. Huffman, Chandan Kumar Tiwari, Jolaine Galindo Betancourth, William W. Brennessel and Brandon R. Barnett
Inorg. Chem., 2023, 62, 11920
DOI: 10.1021/acs.inorgchem.3c01335

Diverse Functionality of Molecular Germanium: Emerging Opportunities as Catalysts
Nilanjana Mukherjee and Moumita Majumdar
J. Am. Chem. Soc., 2024, 146, 24209
DOI: 10.1021/jacs.4c05498

Triel tris(aminoaryl)aluminum, gallium, and indium complexes and their homocoupling reactions mediated by NiBr2
Omar J. Garcia, Mariana L. Díaz-Ramírez, Bruno Donnadieu and Miguel-Ángel Muñoz-Hernández
Polyhedron, 2024, 248, 116752
DOI: 10.1016/j.poly.2023.116752

Rare-Earth Supported Nickel Catalysts for Alkyne Semihydrogenation: Chemo- and Regioselectivity Impacted by the Lewis Acidity and Size of the Support
Bianca L. Ramirez and Connie C. Lu
J. Am. Chem. Soc., 2020, 142, 5396
DOI: 10.1021/jacs.0c00905

Metal‐Free Phosphorus‐Directed Borylation of C(sp2)−H Bonds
Omar Sadek, Arnaud Le Gac, Nereida Hidalgo, Sonia Mallet‐Ladeira, Karinne Miqueu, Ghenwa Bouhadir and Didier Bourissou
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202110102

A N3‐geminal Al/P‐Based Intramolecular Lewis Pair: Synthesis, Characterization and Reactivity
Xiong Sun, Zhuoyi Xie and Lianghua Zou
Eur J Inorg Chem, 2025, 28
DOI: 10.1002/ejic.202400842

Synthesis of Quinoline-Based Rh–Sb Complexes: Inhibition of Halide Transfer to Access a Rh→Sb Z-Type Interaction
Xinrui Ou, Fanji Kong, Kevin P. Quirion, Christopher K. Webber, Diane A. Dickie, Daniel H. Ess and T. Brent Gunnoe
Organometallics, 2025, 44, 1639
DOI: 10.1021/acs.organomet.5c00187

Late 3d-Transition Metal Complexes Bearing a Bis-Phosphine Borane Ligand, PhB(CH2PtBu2)2
Rex C. Handford, Lingfei Zhong and T. Don Tilley
Organometallics, 2022, 41, 2631
DOI: 10.1021/acs.organomet.2c00378

Three-Fold-Symmetric Selenium-Donor Metallaboratranes of Cobalt and Nickel
Stefan Holler, Michael Tüchler, Michaela C. Roschger, Ferdinand Belaj, Luis F. Veiros, Karl Kirchner and Nadia C. Mösch-Zanetti
Inorg. Chem., 2017, 56, 12670
DOI: 10.1021/acs.inorgchem.7b01730

Diferrocenylmercury‐Bridged Diphosphine: A Chiral, Ambiphilic, and Redox‐Active Bidentate Ligand
Alain C. Tagne Kuate, Roger A. Lalancette, Thomas Bannenberg and Frieder Jäkle
Angew Chem Int Ed, 2018, 57, 6552
DOI: 10.1002/anie.201803086

Direct benzylation of amines with benzylic alcohols catalyzed by palladium/phosphine-borane catalyst system
Gen Onodera, Hidenobu Kumagae, Daiki Nakamura, Takuto Hayasaki, Tsutomu Fukuda and Masanari Kimura
Tetrahedron Letters, 2020, 61, 152537
DOI: 10.1016/j.tetlet.2020.152537

Diphosphanylmetallocenes of Main‐Group Elements
Carsten Müller, Joshua Warken, Volker Huch, Bernd Morgenstern, Inga‐Alexandra Bischoff, Michael Zimmer and André Schäfer
Chemistry A European J, 2021, 27, 6500
DOI: 10.1002/chem.202005198

Evaluation of Pd→B Interactions in Diphosphinoborane Complexes and Impact on Inner‐Sphere Reductive Elimination
Florian Ritter, Lukas John, Tobias Schindler, Julian P. Schroers, Simon Teeuwen and Michael E. Tauchert
Chemistry A European J, 2020, 26, 13436
DOI: 10.1002/chem.202001189

Imidazolyl Alanes – Synthesis, Structures, and Reactivity Studies
Martin Simon, Michael Radius, Hanna E. Wagner and Frank Breher
Eur J Inorg Chem, 2020, 2020, 1906
DOI: 10.1002/ejic.202000174

X‐ray structure of host‐guest nanosized organotin supramolecular coordination polymer based on cobalt cyanide and quinoxaline as an efficient catalyst for treatment of waste water
Safaa Eldin H. Etaiw, Dina M. Abd El‐Aziz, Elsayed M. Shalaby and Islam Elzeny
Applied Organom Chemis, 2020, 34
DOI: 10.1002/aoc.5521

N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry
Adinarayana Doddi, Marius Peters and Matthias Tamm
Chem. Rev., 2019, 119, 6994
DOI: 10.1021/acs.chemrev.8b00791

Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers
Angelo Iannetelli, Rosenildo C. Da Costa, Alan J. Guwy, Graham J. Tizzard, Simon J. Coles and Gareth R. Owen
Organometallics, 2020, 39, 1976
DOI: 10.1021/acs.organomet.0c00155

Iron-Indium Complex Catalyzing Selective Double Hydrosilylation, Double Hydroborylation, and Dihydroborylsilylation of a C≡N Bond in Organonitriles
Masumi Itazaki and Hiroshi Nakazawa
J. Syn. Org. Chem., Jpn., 2019, 77, 220
DOI: 10.5059/yukigoseikyokaishi.77.220

A Scandium Metalloligand‐Based Heterobimetallic Pd−Sc Complex: Electronic Tuning Through a Very Short Pd→Sc Dative Bond
Jun Du, Zeming Huang, Yanan Zhang, Shaowu Wang, Shuangliu Zhou, Huayi Fang and Peng Cui
Chemistry A European J, 2019, 25, 10149
DOI: 10.1002/chem.201901424

Siloxyaluminate and Siloxygallate Complexes as Models for Framework and Partially Hydrolyzed Framework Sites in Zeolites and Zeotypes
James P. Dombrowski, Micah S. Ziegler, Neelay M. Phadke, Erum Mansoor, Daniel S. Levine, Ryan J. Witzke, Martin Head‐Gordon, Alexis T. Bell and T. Don Tilley
Chemistry A European J, 2021, 27, 307
DOI: 10.1002/chem.202002926

Development of Catalytic Cross-Coupling Reactions Based on Transition Metal→Z-type Ligand Interactions
Hajime Kameo
J. Synth. Org. Chem. Jpn., 2022, 80, 451
DOI: 10.5059/yukigoseikyokaishi.80.451

The use of [2-C 6 R 4 PPh 2 ] − (R = H, F) and related carbanions as building blocks in coordination chemistry
Martin A. Bennett, Suresh K. Bhargava, Nedaossadat Mirzadeh and Steven H. Privér
Coordination Chemistry Reviews, 2018, 370, 69
DOI: 10.1016/j.ccr.2018.05.008

How Cationic Metalloligands Affect the Coordination of Lewis Basic Ligands in RhIComplexes
Julian P. Schroers, Max N. Kliemann, John M. A. Kollath and Michael E. Tauchert
Organometallics, 2021, 40, 3893
DOI: 10.1021/acs.organomet.1c00449

Functionalised N‐Heterocyclic Carbene Ligands in Bimetallic Architectures
Kieren J. Evans and Stephen M. Mansell
Chemistry A European J, 2020, 26, 5927
DOI: 10.1002/chem.201905510

Modulating the σ-Accepting Properties of an Antimony Z-type Ligand via Anion Abstraction: Remote-Controlled Reactivity of the Coordinated Platinum Atom
Di You, Haifeng Yang, Srobona Sen and François P. Gabbaï
J. Am. Chem. Soc., 2018, 140, 9644
DOI: 10.1021/jacs.8b05520

Amplifying Reactivity of Metal Hydrides: A Heterotrimetallic NiAl2(μ2-H)2 Catalyst for the Dearomatization of N-Heterocycles
Edgardo De Leon, Fernando Gonzalez, Preetika Bauskar, Sergio Gonzalez-Eymard, David De Los Santos and Manar M. Shoshani
Organometallics, 2023, 42, 435
DOI: 10.1021/acs.organomet.2c00668

Inter‐Alkali‐Metal Dative Bond in the MMN3− (M=Alkali Metal) Cluster
Ankur Kanti Guha
ChemPhysChem, 2023, 24
DOI: 10.1002/cphc.202200935

Leveraging Metal and Ligand Reactive Sites for One Pot Reactions: Ligand‐Centered Borenium Ions for Tandem Catalysis with Palladium
Manisha Skaria, Johnathan D. Culpepper and Scott R. Daly
Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201791

Examining the effects of variations in ligand framework and pnictogen substitution on the geometry and electronic structure of metal complexes of N-heterocyclic phosphido ligands incorporated into a diphosphine pincer ligand framework
Christine M. Thomas, Gillian P. Hatzis and Michael J. Pepi
Polyhedron, 2018, 143, 215
DOI: 10.1016/j.poly.2017.11.015

The Phosphinoboration of N‐Heterocycles
Stephen J. Geier, Christopher M. Vogels, Niall R. Mellonie, Erika N. Daley, Andreas Decken, Simon Doherty and Stephen A. Westcott
Chemistry A European J, 2017, 23, 14485
DOI: 10.1002/chem.201702203

Well‐Defined Heterobimetallic Reactivity at Unsupported Ruthenium–Indium Bonds
Ian M. Riddlestone, Nasir A. Rajabi, Stuart A. Macgregor, Mary F. Mahon and Michael K. Whittlesey
Chemistry A European J, 2018, 24, 1732
DOI: 10.1002/chem.201705796

Pnictogen Bonding at the Core of a Carbene-Stiborane-Gold Complex: Impact on Structure and Reactivity
Paula Castro Castro and François P. Gabbaï
Organometallics, 2024, 43, 2334
DOI: 10.1021/acs.organomet.4c00347

Breaking Bonds at Tin(II): Reductive or Oxidative Addition?
Maximilian Dietz, Josef T. Boronski, Amelia M. Swarbrook and Simon Aldridge
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202503050

Photo‐promoted Skeletal Rearrangement of Phosphine–Borane Frustrated Lewis Pairs Involving Cleavage of Unstrained C−C σ‐Bonds
Tatsuyoshi Ito, Nobuharu Iwasawa and Jun Takaya
Angew Chem Int Ed, 2020, 59, 11913
DOI: 10.1002/anie.202004444

Gold-based frustrated Lewis acid/base pairs (FLPs)
Sebastian Arndt, Matthias Rudolph and A. Stephen K. Hashmi
Gold Bull, 2017, 50, 267
DOI: 10.1007/s13404-017-0219-7

Catalytic stannane–fluorine activation triggered by Pd → Sn–F interaction
Hajime Kameo, Yuki Baba and Hiroyuki Matsuzaka
Polyhedron, 2023, 242, 116504
DOI: 10.1016/j.poly.2023.116504

Realization of Lewis Basic Sodium Anion in the NaBH3− Cluster
Gaoxiang Liu, Nikita Fedik, Chalynette Martinez‐Martinez, Sandra M. Ciborowski, Xinxing Zhang, Alexander I. Boldyrev and Kit H. Bowen
Angew Chem Int Ed, 2019, 58, 13789
DOI: 10.1002/anie.201907089

An Antimony(V) Dication as a Z‐Type Ligand: Turning on Styrene Activation at Gold
Ying‐Hao Lo and François P. Gabbaï
Angewandte Chemie, 2019, 131, 10300
DOI: 10.1002/ange.201903964

Racemic and Meso Diastereomers of a P-Chirogenic Diboranyldiphosphinoethane
Brady J. H. Austen, Harvey Sharma, Joseph A. Zurakowski and Marcus W. Drover
Organometallics, 2022, 41, 2709
DOI: 10.1021/acs.organomet.2c00336

Co-Ligand-Dependent Rh(I)–Si(IV) Interactions in Silicon Z-Type Complexes
Nils Ansmann, Jakob H. Alberts, Finn Hagen, Immanuel E. Blaum and Lutz Greb
Inorg. Chem., 2025, 64, 6688
DOI: 10.1021/acs.inorgchem.5c00368

Isolobal Cationic Iridium Dihydride and Dizinc Complexes: A Dual Role for the ZnR Ligand Enhances H2 Activation
Amber M. Walsh, Lia Sotorrios, Rebecca G. Cameron, Anne-Frédérique Pécharman, Barbara Procacci, John P. Lowe, Stuart A. Macgregor, Mary F. Mahon, Neil T. Hunt and Michael K. Whittlesey
Inorg. Chem., 2024, 63, 22944
DOI: 10.1021/acs.inorgchem.4c04058

Hydrosilylation of Terminal Alkenes Catalyzed by a Scandium Metalloligand Supported Ni(0) Complex
Lei Ma, Dongjing Hong and Peng Cui
Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500069

Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes
Ayan Maity and Thomas S. Teets
Chem. Rev., 2016, 116, 8873
DOI: 10.1021/acs.chemrev.6b00034

Fluorosilane Activation by Pd/Ni→Si–F→Lewis Acid Interaction: An Entry to Catalytic Sila-Negishi Coupling
Hajime Kameo, Hiroki Yamamoto, Koki Ikeda, Tomohito Isasa, Shigeyoshi Sakaki, Hiroyuki Matsuzaka, Yago García-Rodeja, Karinne Miqueu and Didier Bourissou
J. Am. Chem. Soc., 2020, 142, 14039
DOI: 10.1021/jacs.0c04690

Cooperative Bond Activation and Facile Intramolecular Aryl Transfer of Nickel–Aluminum Pincer‐type Complexes
Brendan J. Graziano, Matthew V. Vollmer and Connie C. Lu
Angewandte Chemie, 2021, 133, 15214
DOI: 10.1002/ange.202104050

Activation of Dihydrogen and Phenylsilane with Fe(−II) Carbonyl Complexes Enabled by a Lewis Acid in the Secondary Coordination Sphere
Sheng Yan, Cuijuan Zhang and Jiaxiang Chu
Inorg. Chem., 2026
DOI: 10.1021/acs.inorgchem.6c00755

Ambiphilic Molecules: From Organometallic Curiosity to Metal-Free Catalysts
Frédéric-Georges Fontaine and Étienne Rochette
Acc. Chem. Res., 2018, 51, 454
DOI: 10.1021/acs.accounts.7b00514

π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene
Aditesh Mondal, Kevin Breitwieser, Sergi Danés, Annette Grünwald, Frank W. Heinemann, Bernd Morgenstern, Frank Müller, Michael Haumann, Maximilian Schütze, Dustin Kass, Kallol Ray and Dominik Munz
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202418738

meta-Selective C–H Borylation of Benzamides and Pyridines by an Iridium–Lewis Acid Bifunctional Catalyst
Lichen Yang, Nao Uemura and Yoshiaki Nakao
J. Am. Chem. Soc., 2019, 141, 7972
DOI: 10.1021/jacs.9b03138

An Antimony(V) Dication as a Z‐Type Ligand: Turning on Styrene Activation at Gold
Ying‐Hao Lo and François P. Gabbaï
Angew Chem Int Ed, 2019, 58, 10194
DOI: 10.1002/anie.201903964

A Masked Form of an O‐Borylated Breslow Intermediate for the Diastereoselective FLP‐Type Activation of Aldehydes
Angelica Mejia Fajardo, Nicolas Queyriaux, Aurèle Camy, Laure Vendier, Mary Grellier, Iker del Rosal, Laurent Maron and Sébastien Bontemps
Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202104122

Direct Allylation of Active Methylene Compounds with Allylic Alcohols by Use of Palladium/Phosphine‐Borane Catalyst System
Aika Shimizu, Goki Hirata, Gen Onodera and Masanari Kimura
Adv Synth Catal, 2018, 360, 1954
DOI: 10.1002/adsc.201800187

Suzuki coupling catalyzed by chloro({2-[mesityl(quinolin-8-yl-κN)boryl]-3,5-dimethylphenyl}methyl-κC)palladium(II)
Sem Raj Tamang, Andreas J. Achazi, Haley S. Rust, Pramod Dhungana, Pere Miró and James D. Hoefelmeyer
Tetrahedron, 2019, 75, 2365
DOI: 10.1016/j.tet.2019.03.001

Sterically Crowded Gold Germylene Compounds with Methyl and Hydride Substituents
Sonia Bajo, Joaquín López‐Serrano and Jesús Campos
Zeitschrift anorg allge chemie, 2024, 650
DOI: 10.1002/zaac.202400027

Square-Planar Pt(II) and Ir(I) Complexes as the Lewis Bases: Donor–Acceptor Adducts with Group 13 Trihalides and Trihydrides
Zdeněk Chval, Olga Dvořáčková, Daniela Chvalová and Jaroslav V. Burda
Inorg. Chem., 2019, 58, 3616
DOI: 10.1021/acs.inorgchem.8b02765

Insights into H2 Activation and Styrene Hydrogenation by Nickel–Borane and Nickel–Alane Bifunctional Catalysts
Kajjana Boonpalit, Chayapat Uthayopas and Panida Surawatanawong
Organometallics, 2022, 41, 259
DOI: 10.1021/acs.organomet.1c00620

Trigonal-Bipyramidal Pt(0) and Pd(0) Anions
Hajime Kameo, Tokoro Miyazaki, Yoshihiro Shimoyama, Ayaka Asada, Daisuke Izumi, Hiroyuki Matsuzaka and Didier Bourissou
Inorg. Chem., 2024, 63, 13186
DOI: 10.1021/acs.inorgchem.4c01884

Unmasking the Catalytic Activity of a Platinum Complex with a Lewis Acidic, Non-innocent Antimony Ligand
Di You and François P. Gabbaï
J. Am. Chem. Soc., 2017, 139, 6843
DOI: 10.1021/jacs.7b03287

Coordination of the ambiphilic phosphinoborane tBu2PCH2BPh2 to Cu(I)Cl
Devin H.A. Boom, Andreas W. Ehlers, Martin Nieger and J. Chris Slootweg
Zeitschrift für Naturforschung B, 2017, 72, 781
DOI: 10.1515/znb-2017-0078

Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear PtII→GeIV Complex
Mohammadjavad Karimi, Elham S. Tabei, Remi Fayad, Mohamed R. Saber, Evgeny O. Danilov, Cameron Jones, Felix N. Castellano and François P. Gabbaï
Angew Chem Int Ed, 2021, 60, 22352
DOI: 10.1002/anie.202107485

Cationic Complexes with Au→Ge Bonds – Synthesis and Carbophilic Reactivity
Mohammadjavad Karimi, Elishua Litle and François P. Gabbaï†
Israel Journal of Chemistry, 2023, 63
DOI: 10.1002/ijch.202200036

Direct Allylic Amination of Allylic Alcohol Catalyzed by Palladium Complex Bearing Phosphine–Borane Ligand
Goki Hirata, Hideaki Satomura, Hidenobu Kumagae, Aika Shimizu, Gen Onodera and Masanari Kimura
Org. Lett., 2017, 19, 6148
DOI: 10.1021/acs.orglett.7b03023

The Pincer Platform Beyond Classical Coordination Patterns
Matthias Vogt and Robert Langer
Eur J Inorg Chem, 2020, 2020, 3885
DOI: 10.1002/ejic.202000513

Ga/P-Based Ambiphilic Chelates and Their Reactivities with Main Group Elements
Qiannan Wu, Ludwig Zapf, Michael J. Ferguson and Eric Rivard
Inorg. Chem., 2025, 64, 23079
DOI: 10.1021/acs.inorgchem.5c04489

Approaches to homogeneously catalyzed CO hydrogenation: A personal retrospective
Jay A. Labinger
Journal of Organometallic Chemistry, 2017, 847, 4
DOI: 10.1016/j.jorganchem.2017.02.007

Neutral and Anionic Square Planar Palladium(0) Complexes Stabilized by a Silicon Z‐Type Ligand
Nils Ansmann, Joshua Münch, Marcel Schorpp and Lutz Greb
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202313636

Spirosilanes Activate Gold(I)‐Catalysts in Cycloisomerization and Intermolecular Reactions
Lukmonjon Mutalliev, Emilien Beudy, María Ballarín‐Marión, Vincent Delattre, Claire Troufflard, Virginie Mouriès‐Mansuy, Yves Gimbert and Louis Fensterbank
Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.202518534

Diruthenium Catalysis Enables Base‐Free Directed C–H Acylation
Jie Zhao, Yang Chen, Tongxiang Cao and Shifa Zhu
Chin. J. Chem., 2026
DOI: 10.1002/cjoc.70575

Synthesis and Characterization of PBP Pincer Iridium Complexes and Their Application in Alkane Transfer Dehydrogenation
Wei-Chun Shih and Oleg V. Ozerov
Organometallics, 2017, 36, 228
DOI: 10.1021/acs.organomet.6b00762

Ultrasound‐assisted nanoscaled supramolecular coordination polymer as an efficient recyclable catalyst for photocatalytic degradation of dye pollutants
Safaa Eldin H. Etaiw, Tarek A. Fayed, Dina M. Abd El‐Aziz and Hayam M. Khatab
Applied Organom Chemis, 2020, 34
DOI: 10.1002/aoc.5301

Sequential Migrations between Boron and Rhodium Centers: A Cooperative Process between Rhodium and a Monosubstituted Borohydride Unit
Angelo Iannetelli, Graham Tizzard, Simon J. Coles and Gareth R. Owen
Inorg. Chem., 2018, 57, 446
DOI: 10.1021/acs.inorgchem.7b02700

Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination
Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka and Didier Bourissou
Angew Chem Int Ed, 2019, 58, 18783
DOI: 10.1002/anie.201909675

Rh → Sb Interactions Supported by Tris(8-quinolyl)antimony Ligands
Casey R. Wade, Brendan L. Murphy, Shantabh Bedajna and François P. Gabbaï
Organometallics, 2024, 43, 1785
DOI: 10.1021/acs.organomet.4c00258

Diruthenium catalysis: An efficient paradigm for directed C-H functionalization
Jie Zhao, Qifeng Wang, Kai Chen, Ping Chen, Tongxiang Cao and Shifa Zhu
Chinese Chemical Letters, 2026, 112525
DOI: 10.1016/j.cclet.2026.112525

Palladium Complexes Bearing Z-type PAlP Pincer Ligands
Teruhiko Saito, Naofumi Hara and Yoshiaki Nakao
Chem. Lett., 2017, 46, 1247
DOI: 10.1246/cl.170421

ChemInform Abstract: Complexes of Ambiphilic Ligands: Reactivity and Catalytic Applications
Ghenwa Bouhadir and Didier Bourissou
ChemInform, 2016, 47
DOI: 10.1002/chin.201614223

Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid
María L. Buil, Javier A. Cabeza, Miguel A. Esteruelas, Susana Izquierdo, Carlos J. Laglera-Gándara, Antonio I. Nicasio and Enrique Oñate
Inorg. Chem., 2021, 60, 16860
DOI: 10.1021/acs.inorgchem.1c02893

Unusual C–N Coupling Reactivity of Thiopyridazines: Efficient Synthesis of Iron Diorganotrisulfide Complexes
Michael Tüchler, Stefan Holler, Jörg A. Schachner, Ferdinand Belaj and Nadia C. Mösch-Zanetti
Inorg. Chem., 2017, 56, 8159
DOI: 10.1021/acs.inorgchem.7b00865

Transition-Metal-Mediated Germanium–Fluorine Activation: Inverse Electron Flow in σ-Bond Metathesis
Hajime Kameo, Koki Ikeda, Didier Bourissou, Shigeyoshi Sakaki, Shin Takemoto, Hiroshi Nakazawa and Hiroyuki Matsuzaka
Organometallics, 2016, 35, 713
DOI: 10.1021/acs.organomet.5b01000

Substituent Effects in the Cyclization of Yne-Diols Catalyzed by Gold Complexes Featuring L2/Z-Type Diphosphinoborane Ligands
Fuyuhiko Inagaki, Kenta Nakazawa, Kakeru Maeda, Tomoya Koseki and Chisato Mukai
Organometallics, 2017, 36, 3005
DOI: 10.1021/acs.organomet.7b00369

Recent Trends in Group 9 Catalyzed C–H Borylation Reactions: Different Strategies To Control Site-, Regio-, and Stereoselectivity
Lukas Veth, Hanusch A. Grab and Paweł Dydio
Synthesis, 2022, 54, 3482
DOI: 10.1055/a-1711-5889

Rational design of the nickel‐borane complex for efficient hydrogenation of styrene
Lei Zhang, Qin Zhu, Liuzhou Gao, Linlin Yang, Wei Li, Shuhua Li, Jun Zhu, Wei Wang and Guixiang Zeng
J Comput Chem, 2021, 42, 545
DOI: 10.1002/jcc.26480

Heterometallic Mg‐Ni‐Mg Complex Promoted Hydrosilylation of Alkenes: Catalytic Performance and Intermediates Characterization†
Yanping Cai, Shengjie Jiang and Xin Xu
Chin. J. Chem., 2024, 42, 2133
DOI: 10.1002/cjoc.202400176

Cobalt-Group 13 Complexes Catalyze CO2 Hydrogenation via a Co(−I)/Co(I) Redox Cycle
Matthew V. Vollmer, Jingyun Ye, John C. Linehan, Brendan J. Graziano, Andrew Preston, Eric S. Wiedner and Connie C. Lu
ACS Catal., 2020, 10, 2459
DOI: 10.1021/acscatal.9b03534

Realization of Lewis Basic Sodium Anion in the NaBH3− Cluster
Gaoxiang Liu, Nikita Fedik, Chalynette Martinez‐Martinez, Sandra M. Ciborowski, Xinxing Zhang, Alexander I. Boldyrev and Kit H. Bowen
Angewandte Chemie, 2019, 131, 13927
DOI: 10.1002/ange.201907089

Sensing and photocatalytic properties of nanosized Cu(I)CN organotin supramolecular coordination polymer based on pyrazine
Safaa El‐din H. Etaiw, Hassan Marie, Elsayed M. Shalaby, Rabie S. Farag and Fatma A. Elsharqawy
Applied Organom Chemis, 2019, 33
DOI: 10.1002/aoc.5114

Rh-catalyzed aqueous biphasic hydroformylation of higher olefins mediated by guanidinium-based CO2-switchable surfactants
Jinguo Pang, Qi Zhang, Yuhang He and Xin Jin
Chemical Engineering Science, 2025, 316, 121952
DOI: 10.1016/j.ces.2025.121952

Recent advances in boron-centered ligands and their transition metal complexes
James T. Goettel and Holger Braunschweig
Coordination Chemistry Reviews, 2019, 380, 184
DOI: 10.1016/j.ccr.2018.09.013

Octaboraneyl Complexes of Nickel: Monomers for Redox‐Active Coordination Polymers
Marcus W. Drover, Maeve C. Dufour, Lindsay A. Lesperance‐Nantau, Rayni P. Noriega, Kirill Levin and Robert W. Schurko
Chemistry A European J, 2020, 26, 11180
DOI: 10.1002/chem.202001218

Metal→Carbon Dative Bonding
Elishua D. Litle and François P. Gabbaï
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202201841

1,4-Diphosphorinane Synthesis at a Cationic Aluminum(III) Center
Gabriel J. Jobin, Brady J. H. Austen and Marcus W. Drover
Organometallics, 2025, 44, 148
DOI: 10.1021/acs.organomet.4c00415

Synthesis and Reactivity of an Yttrium Hydride Complex Supported by an Arene-Anchored Bis(phosphinomethylamido) Palladium (0) Metalloligand
Hang Shen, Cunyu Song, Dongjing Hong and Peng Cui
Inorg. Chem., 2025, 64, 15562
DOI: 10.1021/acs.inorgchem.5c01897

Lewis Acid-Assisted C(sp3)–C(sp3) Reductive Elimination at Gold
Cyril A. Theulier, Yago García-Rodeja, Karinne Miqueu, Ghenwa Bouhadir and Didier Bourissou
J. Am. Chem. Soc., 2023, 145, 10800
DOI: 10.1021/jacs.3c01974

Three-Coordinate Pd(0) with Rare-Earth Metalloligands: Synergetic CO Activation and Double P–C Bond Cleavage-Formation Reactions
Peng Cui, Changjiang Wu, Jun Du, Gen Luo, Zeming Huang and Shuangliu Zhou
Inorg. Chem., 2021, 60, 9688
DOI: 10.1021/acs.inorgchem.1c00990

Activation of H2 over the Ru−Zn Bond in the Transition Metal−Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt]+
Ian M. Riddlestone, Nasir A. Rajabi, John P. Lowe, Mary F. Mahon, Stuart A. Macgregor and Michael K. Whittlesey
J. Am. Chem. Soc., 2016, 138, 11081
DOI: 10.1021/jacs.6b05243

Reductive CO2 Homocoupling: Synthesis of a Borylated C3 Carbohydrate
Aurélien Béthegnies, Yannick Escudié, Nelson Nuñez‐Dallos, Laure Vendier, John Hurtado, Iker del Rosal, Laurent Maron and Sébastien Bontemps
ChemCatChem, 2019, 11, 760
DOI: 10.1002/cctc.201801875

Modifying Phosphorus(III) Substituents to Activate Remote Ligand-Centered Reactivity in Triaminoborane Ligands
Kyounghoon Lee, Johnathan D. Culpepper, Riffat Parveen, Dale C. Swenson, Bess Vlaisavljevich and Scott R. Daly
Organometallics, 2020, 39, 2526
DOI: 10.1021/acs.organomet.0c00321

Molecularly Controlled Catalysis – Targeting Synergies Between Local and Non‐local Environments
Basujit Chatterjee, Wei‐Chieh Chang and Christophe Werlé
ChemCatChem, 2021, 13, 1659
DOI: 10.1002/cctc.202001431

Inverting Pt–I Bond Polarization to Generate Iodonium Character
Kathleen R. Neff, Kevin Basemann, Neyen Romano, Jennifer J. Becker and Michel R. Gagné
Organometallics, 2023, 42, 2177
DOI: 10.1021/acs.organomet.3c00233

A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO2 and CS2, Activation of H2 and PhCONH2
Marc Devillard, Richard Declercq, Emmanuel Nicolas, Andreas W. Ehlers, Jana Backs, Nathalie Saffon-Merceron, Ghenwa Bouhadir, J. Chris Slootweg, Werner Uhl and Didier Bourissou
J. Am. Chem. Soc., 2016, 138, 4917
DOI: 10.1021/jacs.6b01320

Computational Study on the Role of Zn(II) Z-Type Ligands in Facilitating Diaryl Reductive Elimination from Pt(II)
Chisondi S. Warioba, Logan G. Jackson, Marliss A. Neal and Brandon E. Haines
Organometallics, 2023, 42, 16
DOI: 10.1021/acs.organomet.2c00305

Coordination and Redox Non-innocent Behavior of Hybrid Ligands Containing Tellurium
J. Stuart Jones and François P. Gabbaï
Chem. Lett., 2016, 45, 376
DOI: 10.1246/cl.160103

Implementing the Ambiphilicity of an Organotellurenyl Cation for the Synthesis of a Platinum(II)‐Based Carboxylate‐Bridged Heterobimetallic Complex: Structure and Bonding Analysis
Rajesh Deka, Arup Sarkar, Ray J. Butcher and Harkesh B. Singh
Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202200403

Tuning of Cu–Al Interactions in Complexes Derived from Tris(pyridonyl-6-methyl)aluminum Metalloligands
Omar J. García-de-Jesus, Alexander Mondragón-Díaz, Bruno Donnadieu and Miguel-Ángel Muñoz-Hernández
Inorg. Chem., 2023, 62, 2518
DOI: 10.1021/acs.inorgchem.2c02273

A T-shape diphosphinoborane palladium(0) complex
Patrick Steinhoff and Michael E Tauchert
Beilstein J. Org. Chem., 2016, 12, 1573
DOI: 10.3762/bjoc.12.152

Two synthetic routes to bis(1-methyl-imidazole-2-thione)methane and bis(1-benzyl-imidazole-2-thione)methane complexes including sulfur atom insertion into copper−NHC bonds
Miriam Slivarichova, Rosenildo Correa ​da Costa, Joshua Nunn, Ruua Ahmad, Mairi F. Haddow, Hazel A. Sparkes, Thomas Gray and Gareth R. Owen
Journal of Organometallic Chemistry, 2017, 847, 224
DOI: 10.1016/j.jorganchem.2017.05.015

Anion-Controlled Positional Switching of a Phenyl Group about the Dinuclear Core of a AuSb Complex
Srobona Sen, Iou-Sheng Ke and François P. Gabbaï
Inorg. Chem., 2016, 55, 9162
DOI: 10.1021/acs.inorgchem.6b01290

Di-tert-butyl thiopyridazine boratrane complexes of Co, Ni and Cu
Stefan Holler, Michael Tüchler, Anna M. Knaus, Ferdinand Belaj and Nadia C. Mösch-Zanetti
Polyhedron, 2017, 125, 122
DOI: 10.1016/j.poly.2016.10.021

A PAlP Pincer Ligand Bearing a 2-Diphenylphosphinophenoxy Backbone
Kazuhiko Semba, Ikuya Fujii and Yoshiaki Nakao
Inorganics, 2019, 7, 140
DOI: 10.3390/inorganics7120140

Metal‐Free Phosphorus‐Directed Borylation of C(sp2)−H Bonds
Omar Sadek, Arnaud Le Gac, Nereida Hidalgo, Sonia Mallet‐Ladeira, Karinne Miqueu, Ghenwa Bouhadir and Didier Bourissou
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202110102

The dn Number in Transition Metal Chemistry: Its Utility and Limitations
Nicholas C. Norman and Paul G. Pringle
Chemistry, 2023, 5, 2630
DOI: 10.3390/chemistry5040170

π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene
Aditesh Mondal, Kevin Breitwieser, Sergi Danés, Annette Grünwald, Frank W. Heinemann, Bernd Morgenstern, Frank Müller, Michael Haumann, Maximilian Schütze, Dustin Kass, Kallol Ray and Dominik Munz
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202418738

Dinitrogen Complexes of Cobalt(−I) Supported by Rare-Earth Metal-Based Metalloligands
Yun Zhang, Xiaowei Pan, Min Xu, Chunyan Xiong, Dongjing Hong, Huayi Fang and Peng Cui
Inorg. Chem., 2023, 62, 3836
DOI: 10.1021/acs.inorgchem.2c04099

Synthesis of a C(sp2)‐bridged Phosphine‐Borane by Ionic Coupling
Maxime Boudjelel, Richard Declercq, Sonia Mallet‐Ladeira, Ghenwa Bouhadir and Didier Bourissou
Zeitschrift anorg allge chemie, 2020, 646, 561
DOI: 10.1002/zaac.202000085

Construction of the Oxazolidinone Framework from Propargylamine and CO2 in Air at Ambient Temperature: Catalytic Effect of a Gold Complex Featuring an L2/Z‐Type Ligand
Fuyuhiko Inagaki, Kakeru Maeda, Kenta Nakazawa and Chisato Mukai
Eur J Org Chem, 2018, 2018, 2972
DOI: 10.1002/ejoc.201800228

Frustrated Lewis Pair Chemistry: Searching for New Reactions
Gerald Kehr and Gerhard Erker
Chem. Rec., 2017, 17, 803
DOI: 10.1002/tcr.201700010

Lewis Acidic PSbP Pincer Ligand in Pt-Catalyzed 1,6-Enyne Cycloisomerization: A Theoretical Study
Miao-Miao Zhou, Bei-Lei Jiang, Shao-Fei Ni and Li Dang
J. Org. Chem., 2019, 84, 9454
DOI: 10.1021/acs.joc.9b00794

Mechanism of Si–H Bond Activation for Lewis Acid PBP-Ni-Catalyzed Hydrosilylation of CO2: The Role of the Linear SN2 Type Cooperation
Xiao Huang, Kexin Zhang, Youxiang Shao, Yinwu Li, Fenglong Gu, Ling-Bo Qu, Cunyuan Zhao and Zhuofeng Ke
ACS Catal., 2019, 9, 5279
DOI: 10.1021/acscatal.9b00879

Redox-Active, Boron-Based Ligands in Iron Complexes with Inverted Hydride Reactivity in Dehydrogenation Catalysis
Andreas Bäcker, Yinwu Li, Maximilian Fritz, Maik Grätz, Zhuofeng Ke and Robert Langer
ACS Catal., 2019, 9, 7300
DOI: 10.1021/acscatal.9b00882

Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO2
Jun Takaya and Nobuharu Iwasawa
J. Am. Chem. Soc., 2017, 139, 6074
DOI: 10.1021/jacs.7b02553

Nanoarchitectonics of Palladium Nanoparticles Supported on Carbon‐Based Heterogeneous Catalysts for C─H Activation Reaction
Sahil and Neeraj Gupta
ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202401840

Inverting Palladium–Phosphorus Lewis Pair Formation: Phosphonium Acting as Z‐Type Ligand
Lijun You, Nils Ansmann and Lutz Greb
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202519355

Saturated Heavier Group 14 Compounds as ‐Electron‐Acceptor (Z‐Type) Ligands
Hajime Kameo and Hiroshi Nakazawa
The Chemical Record, 2017, 17, 268
DOI: 10.1002/tcr.201600061

Pd(II)-Mediated Si–H Activation of Ortho-Silyl Arylphosphines: Complexes with Pd–Si Bonds and their Utility in Carbon–Carbon Coupling Reactions
Amiya Kumar Sahoo, Rageshree Dash, Lapislazuli Chekrain Valappil, Gaurav Jhaa, Suraj Kumar Agarwalla, Chandra Shekhar Purohit, Priyakumari Chakkingal Parambil and Adinarayana Doddi
Inorg. Chem., 2025, 64, 20467
DOI: 10.1021/acs.inorgchem.5c03868

Implementation of Cooperative Designs in Polarized Transition Metal Systems—Significance for Bond Activation and Catalysis
Basujit Chatterjee, Wei-Chieh Chang, Soumyashree Jena and Christophe Werlé
ACS Catal., 2020, 10, 14024
DOI: 10.1021/acscatal.0c03794

Dinickela-bicyclo[4,4,0]-decadiene Complex with a Linear Heterometallic Mg–Ni–Ni–Mg Chain
Yanping Cai, Stella Christodoulou, Laurent Maron and Xin Xu
J. Am. Chem. Soc., 2025, 147, 40719
DOI: 10.1021/jacs.5c13473

Bis- and tris-phosphinostannane gold complexes featuring Au → Sn dative interactions: Synthesis, structures, and DFT calculations
Tzu-Pin Lin and François P. Gabbaï
Polyhedron, 2017, 125, 18
DOI: 10.1016/j.poly.2016.07.010

Reactivity of Ru(II) and V(III) complexes of diazafluorene derivatives towards B–H bonds
Trevor Janes, Vincent T. Annibale and Datong Song
Journal of Organometallic Chemistry, 2018, 872, 79
DOI: 10.1016/j.jorganchem.2018.07.025

Cooperative Bond Activation and Facile Intramolecular Aryl Transfer of Nickel–Aluminum Pincer‐type Complexes
Brendan J. Graziano, Matthew V. Vollmer and Connie C. Lu
Angew Chem Int Ed, 2021, 60, 15087
DOI: 10.1002/anie.202104050

Breaking Bonds at Tin(II): Reductive or Oxidative Addition?
Maximilian Dietz, Josef T. Boronski, Amelia M. Swarbrook and Simon Aldridge
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202503050

Square‐Planar Anionic Pt0Complexes
Hajime Kameo, Yudai Tanaka, Yoshihiro Shimoyama, Daisuke Izumi, Hiroyuki Matsuzaka, Yumiko Nakajima, Pierre Lavedan, Arnaud Le Gac and Didier Bourissou
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202301509

Stabilized Carbenium Ions as Latent, Z‐type Ligands
Lewis C. Wilkins, Youngmin Kim, Elishua D. Litle and François P. Gabbaï
Angewandte Chemie, 2019, 131, 18434
DOI: 10.1002/ange.201911662

Tunable σ-Accepting, Z-Type Ligands for Organometallic Catalysis
Di You and François P. Gabbaï
Trends in Chemistry, 2019, 1, 485
DOI: 10.1016/j.trechm.2019.03.011

Synthesis and Characterization of an N-Trifluoromethyl 1,4-Azaborine-Based Phosphine Ligand and Its Transition Metal Complexes
Maxwell Eaton, Tomoya Ozaki, Bo Li and Shih-Yuan Liu
Inorg. Chem., 2026, 65, 5905
DOI: 10.1021/acs.inorgchem.5c05782

Cooperative Catalysis of Combined Systems of Transition‐Metal Complexes with Lewis Acids: Theoretical Understanding
Wei Guan, Guixiang Zeng, Hajime Kameo, Yoshiaki Nakao and Shigeyoshi Sakaki
The Chemical Record, 2016, 16, 2405
DOI: 10.1002/tcr.201600086

Attempted synthesis of ortho -phenylene phosphino-tritylium cations
Kantapat Chansaenpak, Mengxi Yang and François P. Gabbaï
Phil. Trans. R. Soc. A., 2017, 375, 20170007
DOI: 10.1098/rsta.2017.0007

Oxidative‐Insertion Reactivity Across a Geometrically Constrained Metal→Borane Interaction
Brandon R. Barnett, Michael L. Neville, Curtis E. Moore, Arnold L. Rheingold and Joshua S. Figueroa
Angewandte Chemie, 2017, 129, 7301
DOI: 10.1002/ange.201702151

Cooperative Activation of CO and Pyridine by an Aluminum(I) Complex Ligated with a Silylene–Borane Ligand
Jinghuang Lv, Xiao Fang, Fanshu Cao and Zhenbo Mo
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202512084

Nitrogen Fixation via a Terminal Fe(IV) Nitride
Niklas B. Thompson, Michael T. Green and Jonas C. Peters
J. Am. Chem. Soc., 2017, 139, 15312
DOI: 10.1021/jacs.7b09364

Rhodium‐Catalyzed C−H Activation Enabled by an Indium Metalloligand
Ryosuke Yamada, Nobuharu Iwasawa and Jun Takaya
Angew Chem Int Ed, 2019, 58, 17251
DOI: 10.1002/anie.201910197

Addition of O–H, N–H, and F–H Bonds across a Boryl–Iridium Unit
Yihan Cao, Wei-Chun Shih and Oleg V. Ozerov
Organometallics, 2019, 38, 4076
DOI: 10.1021/acs.organomet.8b00785

Oxidative‐Insertion Reactivity Across a Geometrically Constrained Metal→Borane Interaction
Brandon R. Barnett, Michael L. Neville, Curtis E. Moore, Arnold L. Rheingold and Joshua S. Figueroa
Angew Chem Int Ed, 2017, 56, 7195
DOI: 10.1002/anie.201702151

The Elusive Au(I)···H–O Hydrogen Bond: Experimental Verification
Gyeongjin Park and François P. Gabbaï
J. Am. Chem. Soc., 2021, 143, 12494
DOI: 10.1021/jacs.1c07035

The phosphinoboration of 2-diphenylphosphino benzaldehyde and related aldimines
Meagan B. Kindervater, Justin F. Binder, Samuel R. Baird, Christopher M. Vogels, Stephen J. Geier, Charles L.B. Macdonald and Stephen A. Westcott
Journal of Organometallic Chemistry, 2019, 880, 378
DOI: 10.1016/j.jorganchem.2018.11.001

Light‐Driven Hydrodefluorination of Electron‐Rich Aryl Fluorides by an Anionic Rhodium‐Gallium Photoredox Catalyst
James T. Moore, Michael J. Dorantes, Zihan Pengmei, Timothy M. Schwartz, Jacob Schaffner, Samantha L. Apps, Carlo A. Gaggioli, Ujjal Das, Laura Gagliardi, David A. Blank and Connie C. Lu
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202205575

Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts
Liang Liu, Junnian Wei, Yue Chi, Wen‐Xiong Zhang and Zhenfeng Xi
Angew Chem Int Ed, 2016, 55, 14762
DOI: 10.1002/anie.201607355

Versatile binding modes of acyclic N2X2 (X = O, S and P) ligands towards [GeCl]+ and AuCl units
Devesh Maurya, Joy Karmakar, Padmini Sahoo, Ravindra K. Raut and Moumita Majumdar
Inorganica Chimica Acta, 2020, 503, 119380
DOI: 10.1016/j.ica.2019.119380

Charge frustration in ligand design and functional group transfer
Dominik Munz and Karsten Meyer
Nat Rev Chem, 2021, 5, 422
DOI: 10.1038/s41570-021-00276-3

Synthesis, crystal structure, investigation of the intermolecular interactions and catalytic activity of Mn(III) complexes with azide and N2O2-donor ligand
Monireh Darvishvand, Rahman Bikas, Neda Heydari and Maciej Kubicki
Inorganic Chemistry Communications, 2025, 182, 115316
DOI: 10.1016/j.inoche.2025.115316

Photo‐promoted Skeletal Rearrangement of Phosphine–Borane Frustrated Lewis Pairs Involving Cleavage of Unstrained C−C σ‐Bonds
Tatsuyoshi Ito, Nobuharu Iwasawa and Jun Takaya
Angewandte Chemie, 2020, 132, 12011
DOI: 10.1002/ange.202004444

Leveraging molecular metal–support interactions for H2 and N2 activation
Ryan C. Cammarota, Laura J. Clouston and Connie C. Lu
Coordination Chemistry Reviews, 2017, 334, 100
DOI: 10.1016/j.ccr.2016.06.014

Experimental and Theoretical Investigation of an SN2-type Pathway for Borate–Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes
Hajime Kameo, Yuki Baba, Shigeyoshi Sakaki, Yudai Tanaka and Hiroyuki Matsuzaka
Inorg. Chem., 2020, 59, 4282
DOI: 10.1021/acs.inorgchem.9b03053

Coordination- and Redox-Noninnocent Behavior of Ambiphilic Ligands Containing Antimony
J. Stuart Jones and François P. Gabbaï
Acc. Chem. Res., 2016, 49, 857
DOI: 10.1021/acs.accounts.5b00543

Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear PtII→GeIV Complex
Mohammadjavad Karimi, Elham S. Tabei, Remi Fayad, Mohamed R. Saber, Evgeny O. Danilov, Cameron Jones, Felix N. Castellano and François P. Gabbaï
Angewandte Chemie, 2021, 133, 22526
DOI: 10.1002/ange.202107485

Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane
Akira Tanushi and Alexander T. Radosevich
J. Am. Chem. Soc., 2018, 140, 8114
DOI: 10.1021/jacs.8b05156

P–C Bond Cleavage Induced Ni(II) Complexes Bearing Rare-Earth-Metal-Based Metalloligand and Reactivities toward Isonitrile, Nitrile, and Epoxide
Peng Cui, Xia Huang, Jun Du and Zeming Huang
Inorg. Chem., 2021, 60, 3249
DOI: 10.1021/acs.inorgchem.0c03675

Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts
Liang Liu, Junnian Wei, Yue Chi, Wen‐Xiong Zhang and Zhenfeng Xi
Angewandte Chemie, 2016, 128, 14982
DOI: 10.1002/ange.201607355

C−H Silylation of 2‐Arylpyridine Derivatives by Using Iridium Catalyst and Phosphine‐Borane Ligand
Keita Anoyama, Gen Onodera, Tsutomu Fukuda and Masanari Kimura
Adv Synth Catal, 2022, 364, 1223
DOI: 10.1002/adsc.202101476

Synthesis and Characterization of Platinum and Palladium Complexes Featuring a Rare Secondary Borane Pincer Motif
Angelo Iannetelli, Graham Tizzard, Simon J. Coles and Gareth R. Owen
Organometallics, 2018, 37, 2177
DOI: 10.1021/acs.organomet.8b00306

Mechanism of Ir-Mediated Selective Pyridine o-C–H Activation: The Role of Lewis Acidic Boryl Group
Jiahao Liu, Yinwu Li, Jingxing Jiang, Yan Liu and Zhuofeng Ke
ACS Catal., 2021, 11, 6186
DOI: 10.1021/acscatal.1c00310

Structure and Reactivity of [Ru–Al] and [Ru–Sn] Heterobimetallic PPh3-Based Complexes
Connie J. Isaac, Fedor M. Miloserdov, Anne-Frédérique Pécharman, John P. Lowe, Claire L. McMullin and Michael K. Whittlesey
Organometallics, 2022, 41, 2716
DOI: 10.1021/acs.organomet.2c00344

Selective H/D Exchange of Pyridines and Alkylarenes with D2 Enabled by a Heterometallic Mg–Ni–Mg Polyhydride Complex
Yanping Cai, Mengwei Wang, Yueyue Yang and Xin Xu
Inorg. Chem., 2025, 64, 14598
DOI: 10.1021/acs.inorgchem.5c02150

Frustrated Lewis Pairs: Bonding, Reactivity, and Applications
Manas Ghara, Himangshu Mondal, Ranita Pal and Pratim Kumar Chattaraj
J. Phys. Chem. A, 2023, 127, 4561
DOI: 10.1021/acs.jpca.3c02141

Neutral and Anionic Square Planar Palladium(0) Complexes Stabilized by a Silicon Z‐Type Ligand
Nils Ansmann, Joshua Münch, Marcel Schorpp and Lutz Greb
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202313636

Thiopyridazine-Based Copper Boratrane Complexes Demonstrating the Z-type Nature of the Ligand
Stefan Holler, Michael Tüchler, Ferdinand Belaj, Luis F. Veiros, Karl Kirchner and Nadia C. Mösch-Zanetti
Inorg. Chem., 2016, 55, 4980
DOI: 10.1021/acs.inorgchem.6b00464

Phosphine–Borane Ligands Induce Chemoselective Activation and Catalytic Coupling of Acyl Chlorides at Palladium
Maxime Boudjelel, Omar Sadek, Sonia Mallet-Ladeira, Yago García-Rodeja, E. Daiann Sosa Carrizo, Karinne Miqueu, Ghenwa Bouhadir and Didier Bourissou
ACS Catal., 2021, 11, 3822
DOI: 10.1021/acscatal.0c04287

Palladium(II) and Platinum(II) Bis(Stibinidene) Complexes with Intramolecular Hydrogen‐Bond Enforced Geometries
Jan Zechovský, Erik Kertész, Milan Erben, Martin Hejda, Roman Jambor, Aleš Růžička, Zoltán Benkő and Libor Dostál
ChemPlusChem, 2024, 89
DOI: 10.1002/cplu.202300573

Spirosilanes Activate Gold(I)‐Catalysts in Cycloisomerization and Intermolecular Reactions
Lukmonjon Mutalliev, Emilien Beudy, María Ballarín‐Marión, Vincent Delattre, Claire Troufflard, Virginie Mouriès‐Mansuy, Yves Gimbert and Louis Fensterbank
Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.202518534

Rhodium‐Catalyzed C−H Activation Enabled by an Indium Metalloligand
Ryosuke Yamada, Nobuharu Iwasawa and Jun Takaya
Angewandte Chemie, 2019, 131, 17411
DOI: 10.1002/ange.201910197

Thiopyridazine-Based Palladium and Platinum Boratrane Complexes
Stefan Holler, Michael Tüchler, Beate G. Steller, Ferdinand Belaj, Luis F. Veiros, Karl Kirchner and Nadia C. Mösch-Zanetti
Inorg. Chem., 2018, 57, 6921
DOI: 10.1021/acs.inorgchem.8b00530

Phosphine-Disubstituted Gallium and Indium Compounds as Chelators for Transition Metals: Synthesis and Linker-Dependent Photophysical Properties
Ondřej Moždiak, Zdeňka Růžičková, Lukáš Střižík, Libor Dostál, Andreas Steffen and Roman Jambor
Inorg. Chem., 2025, 64, 20382
DOI: 10.1021/acs.inorgchem.5c03622

Direct arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I)
Sem Raj Tamang and James D Hoefelmeyer
Beilstein J. Org. Chem., 2016, 12, 2757
DOI: 10.3762/bjoc.12.272

On the mechanism of homogeneous Pt-catalysis: A theoretical view
Haohua Chen, Yuanyuan Li, Song Liu, Qin Xiong, Ruopeng Bai, Donghui Wei and Yu Lan
Coordination Chemistry Reviews, 2021, 437, 213863
DOI: 10.1016/j.ccr.2021.213863

Light‐Driven Hydrodefluorination of Electron‐Rich Aryl Fluorides by an Anionic Rhodium‐Gallium Photoredox Catalyst
James T. Moore, Michael J. Dorantes, Zihan Pengmei, Timothy M. Schwartz, Jacob Schaffner, Samantha L. Apps, Carlo A. Gaggioli, Ujjal Das, Laura Gagliardi, David A. Blank and Connie C. Lu
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202205575

Diastereoselective tricyclization/dimerization of yne-indoles catalyzed by a Au(III) complex featuring an L2/Z-type ligand
Ryo Murakami, Hiroto Tanishima, Daisuke Naito, Hikari Kawamitsu, Ryoya Kamo, Ayaka Uchida, Kazuki Kawasaki, Chihiro Kiyohara, Motoki Matsuo, Kakeru Maeda and Fuyuhiko Inagaki
Tetrahedron Letters, 2021, 78, 153267
DOI: 10.1016/j.tetlet.2021.153267

A Planar Nickelaspiropentane Complex with Magnesium-Based Metalloligands: Synthesis, Structure, and Synergistic Dihydrogen Activation
Yanping Cai, Shengjie Jiang, Thayalan Rajeshkumar, Laurent Maron and Xin Xu
J. Am. Chem. Soc., 2022, 144, 16647
DOI: 10.1021/jacs.2c07402

Synthesis, Structure, and Reactivity of Molybdenum– and Tungsten–Indane Complexes with Tris(pyrazolyl)borate Ligand
Masumi Itazaki, Kunihisa Nouichi, Ken-ichiro Ookuma, Toshiyuki Moriuchi and Hiroshi Nakazawa
Molecules, 2024, 29, 757
DOI: 10.3390/molecules29040757

Valence and Oxidation State: A Comparison of Their Value and Limitations as Simple Chemical Models
Nicholas C. Norman and Paul G. Pringle
Organometallics, 2025, 44, 1315
DOI: 10.1021/acs.organomet.5c00045

Structurally-Responsive Ligands for High-Performance Catalysts
Johanna M. Blacquiere
ACS Catal., 2021, 11, 5416
DOI: 10.1021/acscatal.1c00613

Exterior decorating: Lewis acid secondary coordination spheres for cooperative reactivity
Joseph A. Zurakowski, Brady J.H. Austen and Marcus W. Drover
Trends in Chemistry, 2022, 4, 331
DOI: 10.1016/j.trechm.2022.01.007

Adding to the Family of Copper Complexes Featuring Borohydride Ligands Based on 2-Mercaptopyridyl Units
Joseph Goldsworthy, Simon D. Thomas, Graham J. Tizzard, Simon J. Coles and Gareth R. Owen
Inorganics, 2019, 7, 93
DOI: 10.3390/inorganics7080093

Highly Functionalized Ferrocenes
Emmanuel Lerayer, Léa Radal, Tuan Anh Nguyen, Nejib Dwadnia, Hélène Cattey, Régine Amardeil, Nadine Pirio, Julien Roger and Jean‐Cyrille Hierso
Eur J Inorg Chem, 2020, 2020, 419
DOI: 10.1002/ejic.201901183

Impact of the Novel Z-Acceptor Ligand Bis{(ortho-diphenylphosphino)phenyl}zinc (ZnPhos) on the Formation and Reactivity of Low-Coordinate Ru(0) Centers
Fedor M. Miloserdov, Connie J. Isaac, Madeleine L. Beck, Arron L. Burnage, James C. B. Farmer, Stuart A. Macgregor, Mary F. Mahon and Michael K. Whittlesey
Inorg. Chem., 2020, 59, 15606
DOI: 10.1021/acs.inorgchem.0c01683

Conformational Switching through the One‐Electron Reduction of an Acridinium‐based, γ‐Cationic Phosphine Gold Complex
Wei‐Chun Liu, Youngmin Kim and François P. Gabbaï
Chemistry A European J, 2021, 27, 6701
DOI: 10.1002/chem.202100389

Invertierte Palladium‐Phosphor Lewis‐Paar Bildung: Phosphonium als Z‐Typ Ligand
Lijun You, Nils Ansmann and Lutz Greb
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202519355

Catalytic Dehydrogenation of (Di)Amine-Boranes with a Geometrically Constrained Phosphine-Borane Lewis Pair
Maxime Boudjelel, E. Daiann Sosa Carrizo, Sonia Mallet−Ladeira, Stéphane Massou, Karinne Miqueu, Ghenwa Bouhadir and Didier Bourissou
ACS Catal., 2018, 8, 4459
DOI: 10.1021/acscatal.8b00152

Mechanistic Investigations on Hydrogenation, Isomerization and Hydrosilylation Reactions Mediated by a Germyl‐Rhodium System
Sonia Bajo, Cyril A. Theulier and Jesús Campos
ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202200157

Stopping Hydrogen Migration in Its Tracks: The First Successful Synthesis of Group Ten Scorpionate Complexes Based on Azaindole Scaffolds
Rosenildo Correa da Costa, Benjamin W. Rawe, Angelo Iannetelli, Graham J. Tizzard, Simon J. Coles, Alan J. Guwy and Gareth R. Owen
Inorg. Chem., 2019, 58, 359
DOI: 10.1021/acs.inorgchem.8b02456

Understanding, Modulating, and Leveraging Transannular M → Z Interactions
Bijoy Ghosh, Felipe Fantuzzi and Ashwini K. Phukan
Inorg. Chem., 2021, 60, 12790
DOI: 10.1021/acs.inorgchem.1c00977

Accessing Ambiphilic Phosphine Boronates through C−H Borylation by an Unforeseen Cationic Iridium Complex
Shawn E. Wright, Stephanie Richardson‐Solorzano, Tiffany N. Stewart, Christopher D. Miller, Kelsey C. Morris, Christopher J. A. Daley and Timothy B. Clark
Angewandte Chemie, 2019, 131, 2860
DOI: 10.1002/ange.201812857

Accessing Ambiphilic Phosphine Boronates through C−H Borylation by an Unforeseen Cationic Iridium Complex
Shawn E. Wright, Stephanie Richardson‐Solorzano, Tiffany N. Stewart, Christopher D. Miller, Kelsey C. Morris, Christopher J. A. Daley and Timothy B. Clark
Angew Chem Int Ed, 2019, 58, 2834
DOI: 10.1002/anie.201812857

Ring-Expansion Reactivity of Ruthenium BB-Carboryne Metallacycle
H. D. A. Chathumal Jayaweera, Mark D. Smith and Dmitry V. Peryshkov
Organometallics, 2024, 43, 2016
DOI: 10.1021/acs.organomet.4c00225

Square‐Planar Anionic Pt0Complexes
Hajime Kameo, Yudai Tanaka, Yoshihiro Shimoyama, Daisuke Izumi, Hiroyuki Matsuzaka, Yumiko Nakajima, Pierre Lavedan, Arnaud Le Gac and Didier Bourissou
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202301509

Computational insights into three-centre four-electron bridging hydride bond in boryl type PBP-M dihydride complexes✰
Yubang Liu, Jiaxin Lin, Huayu Liang, Yinwu Li and Zhuofeng Ke
Chinese Chemical Letters, 2025, 36, 110291
DOI: 10.1016/j.cclet.2024.110291

Phosphine-Directed sp3 C–H, C–O, and C–N Borylation
Kelsey C. Morris, Shawn E. Wright, Gillian F. Meyer and Timothy B. Clark
J. Org. Chem., 2020, 85, 14795
DOI: 10.1021/acs.joc.0c01706

Gold(I) Complexes of the Geminal Phosphinoborane tBu2PCH2BPh2
Devin H. A. Boom, Andreas W. Ehlers, Martin Nieger, Marc Devillard, Ghenwa Bouhadir, Didier Bourissou and J. Chris Slootweg
ACS Omega, 2018, 3, 3945
DOI: 10.1021/acsomega.8b00143

Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands
Connie J. Isaac, Cameron I. Wilson, Arron L. Burnage, Fedor M. Miloserdov, Mary F. Mahon, Stuart A. Macgregor and Michael K. Whittlesey
Inorg. Chem., 2022, 61, 20690
DOI: 10.1021/acs.inorgchem.2c03665

Lewis Acid Transition‐Metal‐Catalyzed Hydrogen Activation: Structures, Mechanisms, and Reactivities
Yinwu Li, Jiahao Liu, Xiao Huang, Ling‐Bo Qu, Cunyuan Zhao, Robert Langer and Zhuofeng Ke
Chemistry A European J, 2019, 25, 13785
DOI: 10.1002/chem.201903193

Activation of an Au−Cl Bond by a Pendent SbIII Lewis Acid: Impact on Structure and Catalytic Activity
J. Stuart Jones and François P. Gabbai
Chemistry A European J, 2017, 23, 1136
DOI: 10.1002/chem.201604521

Theoretical Prediction of Strong Be–B and Be–Al Bonds in [FBeER3]− (E = B, Al; R = H, CH3, Ph) Adducts: Dative or Covalent Bonding?
Palash J. Thakuria, Amit Das and Ankur K. Guha
Inorg. Chem., 2026
DOI: 10.1021/acs.inorgchem.5c05823

Catalytic Hydrogenolysis of Aryl C–F Bonds Using a Bimetallic Rhodium–Indium Complex
James T. Moore and Connie C. Lu
J. Am. Chem. Soc., 2020, 142, 11641
DOI: 10.1021/jacs.0c04937

A Diborylcarbazolyl Ligand for Stabilizing Low-Coordinate and Low-Valent Metal Complexes
Yen-Hua Lee, Wei-Chieh Chang, Hsuan-Wen Fu, Han-Jung Li, Ting-Shen Kuo, Tzuhsiung Yang and Hsueh-Ju Liu
Inorg. Chem., 2026, 65, 4997
DOI: 10.1021/acs.inorgchem.5c05146

Gold-to-Boron Aryl Transfer from a T-Shaped Phosphine–Borane Gold(I) Complex
Cyril A. Theulier, Yago García-Rodeja, Sonia Mallet-Ladeira, Karinne Miqueu, Ghenwa Bouhadir and Didier Bourissou
Organometallics, 2021, 40, 2409
DOI: 10.1021/acs.organomet.1c00364