Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

Rubén Vicente; Eva Tudela; Miguel A. Rodríguez; Ángel L. Suárez-Sobrino; Alfredo Ballesteros

doi:10.1039/D2CC02869G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes†

Rubén Vicente,

*^a Eva Tudela,^a Miguel A. Rodríguez,^b Ángel L. Suárez-Sobrino^a and Alfredo Ballesteros

*^a

Author affiliations

* Corresponding authors

^a Departamento de Química Orgánica e Inorgánica and Instituto Universitario de Química Organometálica “Enrique Moles”, Universidad de Oviedo C/Julian Clavería 8, Oviedo, Spain
E-mail: vicenteruben@uniovi.es

^b Departamento de Química, Centro de Investigación en Síntesis Química, Universidad de la Rioja, Logroño, Spain

Abstract

The synthesis of particular cyclopropane-tethered 1,5-enynes, namely 6-alkynyl-4-alkylidenebicyclo[3.1.0]hex-2-enes, enabled the discovery of unprecedented gold-catalyzed rearrangment to indenes. A computational study of the mechanism of this profound skeleton rearrangement is also disclosed.

This article is part of the themed collection: 2022 Pioneering Investigators

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D2CC02869G
Article type: Communication
Submitted: 20 5月 2022
Accepted: 22 6月 2022
First published: 22 6月 2022

Download Citation

Chem. Commun., 2022,58, 8206-8209

Permissions

Request permissions

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

R. Vicente, E. Tudela, M. A. Rodríguez, Á. L. Suárez-Sobrino and A. Ballesteros, Chem. Commun., 2022, 58, 8206 DOI: 10.1039/D2CC02869G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

Social activity

Search articles by author

Spotlight

Advertisements