Issue 65, 2022

Photoinduced, copper-catalysed direct perfluoroalkylation of heteroarenes

Abstract

An efficient and general process is reported for the photoinduced, copper-catalysed direct perfluoroalkylation of C–H bonds in a broad range of heteroarenes with commercially available perfluoroalkyl iodides. This redox neutral process is simply based on the use of [Cu(bcp)DPEPhos]PF6 as the photoredox catalyst in the presence of potassium acetate and smoothly operates at room temperature.

Graphical abstract: Photoinduced, copper-catalysed direct perfluoroalkylation of heteroarenes

Supplementary files

Article information

Article type
Communication
Submitted
18 4月 2022
Accepted
12 7月 2022
First published
16 7月 2022

Chem. Commun., 2022,58, 9080-9083

Photoinduced, copper-catalysed direct perfluoroalkylation of heteroarenes

H. Baguia, J. Beaudelot, C. Moucheron and G. Evano, Chem. Commun., 2022, 58, 9080 DOI: 10.1039/D2CC02146C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements