Issue 73, 2021

An Ir3L2 complex with anion binding pockets: photocatalytic EZ isomerization via molecular recognition

Abstract

A molecular host with photosensitizing centers provides photo-responsive host–guest properties based on its molecular recognition ability. Here, we construct a self-assembled photoactive Ir(iii) cage-shaped complex that contains anion binding pockets on its rim. The anion recognition ability of the complex enables efficient catalysis of the visible-light-induced EZ isomerization of an anionic styrene derivative.

Graphical abstract: An Ir3L2 complex with anion binding pockets: photocatalytic E–Z isomerization via molecular recognition

Supplementary files

Article information

Article type
Communication
Submitted
06 7月 2021
Accepted
16 8月 2021
First published
16 8月 2021

Chem. Commun., 2021,57, 9300-9302

An Ir3L2 complex with anion binding pockets: photocatalytic EZ isomerization via molecular recognition

H. Sunohara, K. Koyamada, H. Takezawa and M. Fujita, Chem. Commun., 2021, 57, 9300 DOI: 10.1039/D1CC03620C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements