Issue 15, 2017

Heterogeneous catalytic hydrogenation of CO2 by metal oxides: defect engineering – perfecting imperfection

Abstract

Metal oxides with their myriad compositions, structures and bonding exhibit an incredibly diverse range of properties. It is however the defects in metal oxides that endow them with a variety of functions and it is the ability to chemically tailor the type, population and distribution of defects on the surface and in the bulk of metal oxides that delivers utility in different applications. In this Tutorial Review, we discuss how metal oxides with designed defects can be synthesized and engineered, to enable heterogeneous catalytic hydrogenation of gaseous carbon dioxide to chemicals and fuels. If this approach to utilization and valorization of carbon dioxide could be developed at industrially significant rates, efficiencies and scales and made economically competitive with fossil-based chemicals and fuels, then carbon dioxide refineries envisioned in the future would be able to contribute to the reduction of greenhouse gas emissions, ameliorate climate changes, provide energy security and enable protection of the environment. This would bring the vision of a sustainable future closer to reality.

Graphical abstract: Heterogeneous catalytic hydrogenation of CO2 by metal oxides: defect engineering – perfecting imperfection

Article information

Article type
Tutorial Review
Submitted
17 1月 2017
First published
21 6月 2017

Chem. Soc. Rev., 2017,46, 4631-4644

Heterogeneous catalytic hydrogenation of CO2 by metal oxides: defect engineering – perfecting imperfection

J. Jia, C. Qian, Y. Dong, Y. F. Li, H. Wang, M. Ghoussoub, K. T. Butler, A. Walsh and G. A. Ozin, Chem. Soc. Rev., 2017, 46, 4631 DOI: 10.1039/C7CS00026J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements