Issue 53, 2022

Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Abstract

The photoactivation mechanism of Os3(CO)12 at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os3(CO)11 with a ligand vacancy at the axial position.

Graphical abstract: Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Supplementary files

Article information

Article type
Communication
Submitted
02 5月 2022
Accepted
07 6月 2022
First published
08 6月 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 7380-7383

Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

H. Ki, T. W. Kim, J. Moon, J. Kim, Y. Lee, J. Heo, K. H. Kim, Q. Kong, D. Khakhulin, G. Newby, J. Kim, J. Kim, M. Wulff and H. Ihee, Chem. Commun., 2022, 58, 7380 DOI: 10.1039/D2CC02438A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements