Issue 7, 2021

Effect of commensurate lithium doping on the scintillation of two-dimensional perovskite crystals

Abstract

Two-dimensional (2D) hybrid lead bromide perovskites are candidates for high light yield, fast scintillators. In this paper, we discuss the effect of commensurate Lithium (Li)-doping (1 : 1 Li : Pb precursor ratio) on the scintillation properties of two previously reported high light yield 2D-perovskite crystals, PEA2PbBr4 and BA2PbBr4. The effect of Li, e.g. light yield enhancement, is more prominent in PEA2PbBr4 compared to BA2PbBr4. Both perovskite crystals show a broadening of the radioluminescence spectrum and a slightly longer afterglow, with residual scintillation below 2% after 5 s for both materials. The effects of Li on the negative thermal quenching exhibited by the perovskites are also discussed. Li doping increases the light yield of PEA2PbBr4 by 78% and both perovskite materials show an improvement in their energy resolutions, with a record of 7.7% at 662 keV for the Li-doped PEA2PbBr4. Both perovskite crystals also show very fast gamma-ray excited scintillation decays, with average times of 12.9 ns and 8.0 ns for PEA2PbBr4 and BA2PbBr4, respectively. This work shows that Li doping brings a significant improvement of the perovskite performance, making the perovskites more competitive for fast, high light yield applications in the medical, security or industrial sectors.

Graphical abstract: Effect of commensurate lithium doping on the scintillation of two-dimensional perovskite crystals

Supplementary files

Article information

Article type
Paper
Submitted
01 12月 2020
Accepted
16 1月 2021
First published
18 1月 2021

J. Mater. Chem. C, 2021,9, 2504-2512

Effect of commensurate lithium doping on the scintillation of two-dimensional perovskite crystals

F. Maddalena, A. Xie, Arramel, M. E. Witkowski, M. Makowski, B. Mahler, W. Drozdowski, T. Mariyappan, S. V. Springham, P. Coquet, C. Dujardin, M. D. Birowosuto and C. Dang, J. Mater. Chem. C, 2021, 9, 2504 DOI: 10.1039/D0TC05647B

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