Issue 18, 2021

Selective C(sp3)–H activation of simple alkanes: visible light-induced metal-free synthesis of phenanthridines with H2O2 as a sustainable oxidant

Abstract

The visible light-induced metal-free C(sp3)–H phenanthridinylation of simple alkanes with isonitrile is developed with H2O2 as a terminal green oxidant. This reaction features good yields and selectivities, mild conditions, and a broad substrate scope with gaseous alkanes involved, allowing practical access to valuable alkyl-substituted phenanthridine derivatives.

Graphical abstract: Selective C(sp3)–H activation of simple alkanes: visible light-induced metal-free synthesis of phenanthridines with H2O2 as a sustainable oxidant

Supplementary files

Article information

Article type
Communication
Submitted
26 7月 2021
Accepted
18 8月 2021
First published
18 8月 2021

Green Chem., 2021,23, 6926-6930

Selective C(sp3)–H activation of simple alkanes: visible light-induced metal-free synthesis of phenanthridines with H2O2 as a sustainable oxidant

Y. Zhang, Y. Jin, L. Wang, Q. Zhang, C. Meng and C. Duan, Green Chem., 2021, 23, 6926 DOI: 10.1039/D1GC02670D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements