Issue 20, 2018

A renaissance of ligand-to-metal charge transfer by cerium photocatalysis

Abstract

With the flourishing progress of photochemistry, many electron transfer mechanisms have been developed to explain the interactions of intermediates, such as MLCT, LMCT, and PCET. Diverse alcohols, serving as substrates or co-catalysts, and Ce(IV) achieve photoinduced LMCT to generate highly active alkoxy radicals, which opens a new avenue for many difficult HAT reactions. It's believed that more valuable applications of LMCTs will be developed in the future.

Graphical abstract: A renaissance of ligand-to-metal charge transfer by cerium photocatalysis

Article information

Article type
Highlight
Submitted
19 8月 2018
Accepted
02 9月 2018
First published
03 9月 2018

Org. Chem. Front., 2018,5, 3018-3021

A renaissance of ligand-to-metal charge transfer by cerium photocatalysis

R. Zhao and L. Shi, Org. Chem. Front., 2018, 5, 3018 DOI: 10.1039/C8QO00893K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements